Synthesis and characterisation of linked triosmium clusters using the bis(diphenylphosphino)acetylene ligand

Brian F.G. Johnson, Jack Lewis, Anju Deepali Massey, Paul R. Raithby, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

17 Citations (Scopus)

Abstract

The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords [Os3(CO)11]2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2with an excess of dppa gives [Os3(CO)10(dppa)]3(2) and [Os3(CO)10(dppa)]4(3) in moderate yields. The structure of 1 has been determined by a single crystal X-ray diffraction study.
Original languageEnglish
JournalJournal of Organometallic Chemistry
Volume397
Issue number2
DOIs
Publication statusPublished - 6 Nov 1990
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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