Synthesis and characterisation of linked triosmium clusters using the bis(diphenylphosphino)acetylene ligand

Brian F.G. Johnson; Jack Lewis; Anju Deepali Massey; Paul R. Raithby; Wing Tak Wong

doi:10.1016/0022-328X(90)80247-W

Synthesis and characterisation of linked triosmium clusters using the bis(diphenylphosphino)acetylene ligand

Brian F.G. Johnson, Jack Lewis, Anju Deepali Massey, Paul R. Raithby, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

16 Citations (Scopus)

Abstract

The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords [Os3(CO)11]2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2with an excess of dppa gives [Os3(CO)10(dppa)]3(2) and [Os3(CO)10(dppa)]4(3) in moderate yields. The structure of 1 has been determined by a single crystal X-ray diffraction study.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	397
Issue number	2
DOIs	https://doi.org/10.1016/0022-328X(90)80247-W
Publication status	Published - 6 Nov 1990
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(90)80247-W

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title = "Synthesis and characterisation of linked triosmium clusters using the bis(diphenylphosphino)acetylene ligand",

abstract = "The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords [Os3(CO)11]2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2with an excess of dppa gives [Os3(CO)10(dppa)]3(2) and [Os3(CO)10(dppa)]4(3) in moderate yields. The structure of 1 has been determined by a single crystal X-ray diffraction study.",

author = "Johnson, {Brian F.G.} and Jack Lewis and Massey, {Anju Deepali} and Raithby, {Paul R.} and Wong, {Wing Tak}",

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AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Massey, Anju Deepali

AU - Raithby, Paul R.

AU - Wong, Wing Tak

PY - 1990/11/6

Y1 - 1990/11/6

N2 - The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords [Os3(CO)11]2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2with an excess of dppa gives [Os3(CO)10(dppa)]3(2) and [Os3(CO)10(dppa)]4(3) in moderate yields. The structure of 1 has been determined by a single crystal X-ray diffraction study.

AB - The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords [Os3(CO)11]2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2with an excess of dppa gives [Os3(CO)10(dppa)]3(2) and [Os3(CO)10(dppa)]4(3) in moderate yields. The structure of 1 has been determined by a single crystal X-ray diffraction study.

UR - http://www.scopus.com/inward/record.url?scp=0012989265&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(90)80247-W

DO - 10.1016/0022-328X(90)80247-W

M3 - Journal article

SN - 0022-328X

VL - 397

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Synthesis and characterisation of linked triosmium clusters using the bis(diphenylphosphino)acetylene ligand

Abstract

ASJC Scopus subject areas

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