Abstract
The reaction of the triosmium cluster anion, [Os3(μ-H)(CO) 11][PPN] (PPN = [N(PPh3)2]+), with [AgPF6] in the presence of [Ir(PPh3)2(CO)Cl] in THF at room temperature affords two new high-nuclearity osmium-silver clusters, [Os13Ag9(CO)48][PPN] (1) and [Os 9Ag9(μ3-O)2(CO) 30][PPN] (2), and an iridium complex, [Ir(PPh3) 2(CO)Cl(O2)] (3).
Original language | English |
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Pages (from-to) | 3924-3926 |
Number of pages | 3 |
Journal | Chemical Communications |
Issue number | 38 |
DOIs | |
Publication status | Published - 1 Dec 2007 |
Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry