Synthesis and characterisation of high-nuclearity osmium-silver mixed-metal clusters

Yui Bing Lee, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

5 Citations (Scopus)

Abstract

The reaction of the triosmium cluster anion, [Os3(μ-H)(CO) 11][PPN] (PPN = [N(PPh3)2]+), with [AgPF6] in the presence of [Ir(PPh3)2(CO)Cl] in THF at room temperature affords two new high-nuclearity osmium-silver clusters, [Os13Ag9(CO)48][PPN] (1) and [Os 9Ag9(μ3-O)2(CO) 30][PPN] (2), and an iridium complex, [Ir(PPh3) 2(CO)Cl(O2)] (3).
Original languageEnglish
Pages (from-to)3924-3926
Number of pages3
JournalChemical Communications
Issue number38
DOIs
Publication statusPublished - 1 Dec 2007
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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