Syntheses of linked ruthenium and osmium carbonyl clusters containing a bridging oxalato ligand: X-ray structures of [{Os3(μ-H) (CO) 10}2(C2O4)] and [{Ru 5(μ-H)C(CO)14}2(C2O4)]

Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Vijay P. Saharan; Wing Tak Wong

doi:10.1039/C39910000365

Syntheses of linked ruthenium and osmium carbonyl clusters containing a bridging oxalato ligand: X-ray structures of [{Os₃(μ-H) (CO) ₁₀}₂(C₂O₄)] and [{Ru ₅(μ-H)C(CO)₁₄}₂(C₂O₄)]

Brian F.G. Johnson
, Jack Lewis
, Paul R. Raithby
, Vijay P. Saharan
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

21 Citations (Scopus)

Abstract

The reaction of oxalic acid (H2C2O4) with 2 equivalents of [Os3(CO)10(MeCN)2] in CH 2Cl2 yields yellow crystals of [{Os3(μ-H) (CO)10}2(C2O4)] 1 in good yield, while treatment of [Ru5C(CO)15] with 2 equivalents of oxalic acid affords [Ru5(μ-H)C(CO)14} 2(C2O4)] 2 in low yield; the structures of 1 and 2 have been established by X-ray crystallography.

Original language	English
Pages (from-to)	365-367
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/C39910000365
Publication status	Published - 1 Dec 1991
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

More information

10.1039/C39910000365

Cite this

Johnson, B. F. G., Lewis, J., Raithby, P. R., Saharan, V. P., & Wong, W. T. (1991). Syntheses of linked ruthenium and osmium carbonyl clusters containing a bridging oxalato ligand: X-ray structures of [{Os₃(μ-H) (CO) ₁₀}₂(C₂O₄)] and [{Ru ₅(μ-H)C(CO)₁₄}₂(C₂O₄)]. Journal of the Chemical Society, Chemical Communications, (6), 365-367. https://doi.org/10.1039/C39910000365

@article{44e731aebbfa49289e834b14bcaaa129,

title = "Syntheses of linked ruthenium and osmium carbonyl clusters containing a bridging oxalato ligand: X-ray structures of [\{Os3(μ-H) (CO) 10\}2(C2O4)] and [\{Ru 5(μ-H)C(CO)14\}2(C2O4)]",

abstract = "The reaction of oxalic acid (H2C2O4) with 2 equivalents of [Os3(CO)10(MeCN)2] in CH 2Cl2 yields yellow crystals of [\{Os3(μ-H) (CO)10\}2(C2O4)] 1 in good yield, while treatment of [Ru5C(CO)15] with 2 equivalents of oxalic acid affords [Ru5(μ-H)C(CO)14\} 2(C2O4)] 2 in low yield; the structures of 1 and 2 have been established by X-ray crystallography.",

author = "Johnson, \{Brian F.G.\} and Jack Lewis and Raithby, \{Paul R.\} and Saharan, \{Vijay P.\} and Wong, \{Wing Tak\}",

year = "1991",

month = dec,

day = "1",

doi = "10.1039/C39910000365",

language = "English",

pages = "365--367",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "6",

}

Syntheses of linked ruthenium and osmium carbonyl clusters containing a bridging oxalato ligand: X-ray structures of [{Os₃(μ-H) (CO) ₁₀}₂(C₂O₄)] and [{Ru ₅(μ-H)C(CO)₁₄}₂(C₂O₄)]. / Johnson, Brian F.G.; Lewis, Jack; Raithby, Paul R. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 6, 01.12.1991, p. 365-367.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Syntheses of linked ruthenium and osmium carbonyl clusters containing a bridging oxalato ligand: X-ray structures of [{Os3(μ-H) (CO) 10}2(C2O4)] and [{Ru 5(μ-H)C(CO)14}2(C2O4)]

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Saharan, Vijay P.

AU - Wong, Wing Tak

PY - 1991/12/1

Y1 - 1991/12/1

N2 - The reaction of oxalic acid (H2C2O4) with 2 equivalents of [Os3(CO)10(MeCN)2] in CH 2Cl2 yields yellow crystals of [{Os3(μ-H) (CO)10}2(C2O4)] 1 in good yield, while treatment of [Ru5C(CO)15] with 2 equivalents of oxalic acid affords [Ru5(μ-H)C(CO)14} 2(C2O4)] 2 in low yield; the structures of 1 and 2 have been established by X-ray crystallography.

AB - The reaction of oxalic acid (H2C2O4) with 2 equivalents of [Os3(CO)10(MeCN)2] in CH 2Cl2 yields yellow crystals of [{Os3(μ-H) (CO)10}2(C2O4)] 1 in good yield, while treatment of [Ru5C(CO)15] with 2 equivalents of oxalic acid affords [Ru5(μ-H)C(CO)14} 2(C2O4)] 2 in low yield; the structures of 1 and 2 have been established by X-ray crystallography.

UR - https://www.scopus.com/pages/publications/37049071133

U2 - 10.1039/C39910000365

DO - 10.1039/C39910000365

M3 - Journal article

SN - 0022-4936

SP - 365

EP - 367

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 6

ER -

Syntheses of linked ruthenium and osmium carbonyl clusters containing a bridging oxalato ligand: X-ray structures of [{Os₃(μ-H) (CO) ₁₀}₂(C₂O₄)] and [{Ru ₅(μ-H)C(CO)₁₄}₂(C₂O₄)]

Abstract

ASJC Scopus subject areas

More information

Other files and links

Fingerprint

Cite this