Syntheses, crystal structures and spectroelectrochemical studies of two isomeric binuclear osmium carbonyl compounds [{Os(CO)2Ph}2{μ-η2-SC(NNPh)2}2]

Fung Sze Kong, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

3 Citations (Scopus)

Abstract

Treatment of (diphenylthiocarbazono)phenylmercury [PhHg{SC(NNPh)2}] with the triosmium cluster [Os3(CO)10(NCMe)2] produced two structural isomers 1a and 1b of formulae [{Os(CO)2Ph}2{μ-η2-SC(NNPh)2}2] in 35 and 20% yield, respectively. The complexes were fully characterised by IR,1H-NMR, mass spectroscopies and X-ray crystallography. The isomers 1a and 1b show no significant metal-metal interaction and are different in the arrangement of the organic ligand. Complex 1a was found to undergo a complete conversion to 1b in the presence of excess reducing agent Co(Cp)2. The electrochemical and spectroelectrochemical (UV-vis) properties of these two complexes are described.
Original languageEnglish
Pages (from-to)191-197
Number of pages7
JournalJournal of Organometallic Chemistry
Volume589
Issue number2
DOIs
Publication statusPublished - 5 Nov 1999
Externally publishedYes

Keywords

  • Diphenylthiocarbazono
  • Osmium
  • Spectrochemical

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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