Syntheses and structures of novel heterobimetallic Cu(li)-Au(i) complexes Cu(cyclen)[Au(CN)2]2 and Cu(pyz)[Au(CN)2]2

Wai Fun Yeung; Wing Tak Wong; Jing Lin Zuo; Tai Chu Lau

doi:10.1039/a910350n

Syntheses and structures of novel heterobimetallic Cu(li)-Au(i) complexes Cu(cyclen)[Au(CN)2]2 and Cu(pyz)[Au(CN)2]2

Wai Fun Yeung, Wing Tak Wong, Jing Lin Zuo, Tai Chu Lau

Research output: Journal article publication › Journal article › Academic research › peer-review

43 Citations (Scopus)

Abstract

Two novel cyano CuII-AuI bimetallic complexes, Cu(cyclen)[Au(CN)2]2 1 (cyclen = 1,4,7,10-tetraazacyclododecanc) and Cu(pyz)[Au(CN)2]22 (pyz = pyrazine) were prepared; 1 has a dimeric structure arising from Au1 ... Au1 interactions, while 2 consists of linear pyrazine-bridged copper chains intercalated to produce a 2-D pleated sheet structure.

Original language	English
Pages (from-to)	629-631
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	5
DOIs	https://doi.org/10.1039/a910350n
Publication status	Published - 1 Dec 2000
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1039/a910350n

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title = "Syntheses and structures of novel heterobimetallic Cu(li)-Au(i) complexes Cu(cyclen)[Au(CN)2]2 and Cu(pyz)[Au(CN)2]2",

abstract = "Two novel cyano CuII-AuI bimetallic complexes, Cu(cyclen)[Au(CN)2]2 1 (cyclen = 1,4,7,10-tetraazacyclododecanc) and Cu(pyz)[Au(CN)2]22 (pyz = pyrazine) were prepared; 1 has a dimeric structure arising from Au1 ... Au1 interactions, while 2 consists of linear pyrazine-bridged copper chains intercalated to produce a 2-D pleated sheet structure.",

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AU - Wong, Wing Tak

AU - Zuo, Jing Lin

AU - Lau, Tai Chu

PY - 2000/12/1

Y1 - 2000/12/1

N2 - Two novel cyano CuII-AuI bimetallic complexes, Cu(cyclen)[Au(CN)2]2 1 (cyclen = 1,4,7,10-tetraazacyclododecanc) and Cu(pyz)[Au(CN)2]22 (pyz = pyrazine) were prepared; 1 has a dimeric structure arising from Au1 ... Au1 interactions, while 2 consists of linear pyrazine-bridged copper chains intercalated to produce a 2-D pleated sheet structure.

AB - Two novel cyano CuII-AuI bimetallic complexes, Cu(cyclen)[Au(CN)2]2 1 (cyclen = 1,4,7,10-tetraazacyclododecanc) and Cu(pyz)[Au(CN)2]22 (pyz = pyrazine) were prepared; 1 has a dimeric structure arising from Au1 ... Au1 interactions, while 2 consists of linear pyrazine-bridged copper chains intercalated to produce a 2-D pleated sheet structure.

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Syntheses and structures of novel heterobimetallic Cu(li)-Au(i) complexes Cu(cyclen)[Au(CN)2]2 and Cu(pyz)[Au(CN)2]2

Abstract

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