Syntheses and structural characterisation of triosmium carbonyl clusters containing bis(diphenylthiophosphinoyl)amine

Emmie Ngai Man Ho; Wing Tak Wong

Syntheses and structural characterisation of triosmium carbonyl clusters containing bis(diphenylthiophosphinoyl)amine

Emmie Ngai Man Ho
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

Abstract

The reaction of [Os3(CO)11(NCMe)] with bis(diphenylthiophosphinoyl)amine [Ph2P(S)NHP(S)Ph2] in dichloromethane at room temperature afforded two yellow products [Os3(CO)10{Ph2P(SH)NP(S)Ph2-S,S}] and [Os3H(CO)9{Ph2P(S)NP(S)Ph2-S,S}] in which the ligand adopts a novel co-ordination mode.

Original language	English
Pages (from-to)	915-916
Number of pages	2
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	6
Publication status	Published - 21 Mar 1997
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

Cite this

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title = "Syntheses and structural characterisation of triosmium carbonyl clusters containing bis(diphenylthiophosphinoyl)amine",

abstract = "The reaction of [Os3(CO)11(NCMe)] with bis(diphenylthiophosphinoyl)amine [Ph2P(S)NHP(S)Ph2] in dichloromethane at room temperature afforded two yellow products [Os3(CO)10\{Ph2P(SH)NP(S)Ph2-S,S\}] and [Os3H(CO)9\{Ph2P(S)NP(S)Ph2-S,S\}] in which the ligand adopts a novel co-ordination mode.",

author = "Ho, \{Emmie Ngai Man\} and Wong, \{Wing Tak\}",

year = "1997",

month = mar,

day = "21",

language = "English",

pages = "915--916",

journal = "Journal of the Chemical Society - Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "6",

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TY - JOUR

T1 - Syntheses and structural characterisation of triosmium carbonyl clusters containing bis(diphenylthiophosphinoyl)amine

AU - Ho, Emmie Ngai Man

AU - Wong, Wing Tak

PY - 1997/3/21

Y1 - 1997/3/21

N2 - The reaction of [Os3(CO)11(NCMe)] with bis(diphenylthiophosphinoyl)amine [Ph2P(S)NHP(S)Ph2] in dichloromethane at room temperature afforded two yellow products [Os3(CO)10{Ph2P(SH)NP(S)Ph2-S,S}] and [Os3H(CO)9{Ph2P(S)NP(S)Ph2-S,S}] in which the ligand adopts a novel co-ordination mode.

AB - The reaction of [Os3(CO)11(NCMe)] with bis(diphenylthiophosphinoyl)amine [Ph2P(S)NHP(S)Ph2] in dichloromethane at room temperature afforded two yellow products [Os3(CO)10{Ph2P(SH)NP(S)Ph2-S,S}] and [Os3H(CO)9{Ph2P(S)NP(S)Ph2-S,S}] in which the ligand adopts a novel co-ordination mode.

UR - https://www.scopus.com/pages/publications/33748574612

M3 - Journal article

SN - 0300-9246

SP - 915

EP - 916

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 6

ER -

Syntheses and structural characterisation of triosmium carbonyl clusters containing bis(diphenylthiophosphinoyl)amine

Abstract

ASJC Scopus subject areas

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