Syntheses and structural characterisation of triosmium carbonyl clusters containing bis(diphenylthiophosphinoyl)amine

Emmie Ngai Man Ho, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

11 Citations (Scopus)

Abstract

The reaction of [Os3(CO)11(NCMe)] with bis(diphenylthiophosphinoyl)amine [Ph2P(S)NHP(S)Ph2] in dichloromethane at room temperature afforded two yellow products [Os3(CO)10{Ph2P(SH)NP(S)Ph2-S,S}] and [Os3H(CO)9{Ph2P(S)NP(S)Ph2-S,S}] in which the ligand adopts a novel co-ordination mode.
Original languageEnglish
Pages (from-to)915-916
Number of pages2
JournalJournal of the Chemical Society - Dalton Transactions
Issue number6
Publication statusPublished - 21 Mar 1997
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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