Syntheses and characterization of high-nuclearity osmium-palladium mixed-metal carbonyl clusters; molecular structures of [Os4Pd6(CO)8-(μ-CO)5(μ3-CO)3(μ-dppm)2]·0.5C6H14and [Os5Pd4(μ6-C)(CO)12-(μ-CO)3(μ-dppm) ...

Janesse Wing Sze Hui; Wing Tak Wong

Syntheses and characterization of high-nuclearity osmium-palladium mixed-metal carbonyl clusters; molecular structures of [Os₄Pd₆(CO)₈-(μ-CO)₅(μ₃-CO)₃(μ-dppm)₂]·0.5C₆H₁₄and [Os₅Pd₄(μ₆-C)(CO)₁₂-(μ-CO)₃(μ-dppm) ...

Janesse Wing Sze Hui, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

Abstract

Title full: Syntheses and characterization of high-nuclearity osmium-palladium mixed-metal carbonyl clusters; molecular structures of [Os4Pd6(CO)8-(μ-CO)5(μ3-CO)3(μ-dppm)2]·0.5C6H14and [Os5Pd4(μ6-C)(CO)12-(μ-CO)3(μ-dppm)2]·CH2Cl2. Treatment of [Os3(CO)10(μ-H)2] with [Pd2(μ-dppm)2Cl2] afforded the novel high-nuclearity osmium-palladium mixed-metal carbonyl clusters [Os5Pd6(CO)13(μ-CO)5(μ-H)2(μ-dppm)2] 1, [Os5Pd6(CO)13(μ-CO)6(μ-dppm)2] 2 and [Os4Pd6(CO)8(μ-CO)8(μ-dppm)2] 3 in low yield, while the reaction of [Os3(μ5-C)(CO)15] with [Pd2(μ-dppm)2Cl2] afforded [Os5Pd4(μ6-C)(CO)12(μ-CO)3(μ-dppm)2] 4 and [Os5(μ5-C)(CO)13(μ-dppm)] 5 in moderate yields. The molecular structures of clusters 3 and 4 have been determined.

Original language	English
Pages (from-to)	2065-2070
Number of pages	6
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	12
Publication status	Published - 21 Jun 1998
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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@article{60b2fc474ad84fb6be598828b57e9bdb,

title = "Syntheses and characterization of high-nuclearity osmium-palladium mixed-metal carbonyl clusters; molecular structures of [Os4Pd6(CO)8-(μ-CO)5(μ3-CO)3(μ-dppm)2]·0.5C6H14and [Os5Pd4(μ6-C)(CO)12-(μ-CO)3(μ-dppm) ...",

abstract = "Title full: Syntheses and characterization of high-nuclearity osmium-palladium mixed-metal carbonyl clusters; molecular structures of [Os4Pd6(CO)8-(μ-CO)5(μ3-CO)3(μ-dppm)2]·0.5C6H14and [Os5Pd4(μ6-C)(CO)12-(μ-CO)3(μ-dppm)2]·CH2Cl2. Treatment of [Os3(CO)10(μ-H)2] with [Pd2(μ-dppm)2Cl2] afforded the novel high-nuclearity osmium-palladium mixed-metal carbonyl clusters [Os5Pd6(CO)13(μ-CO)5(μ-H)2(μ-dppm)2] 1, [Os5Pd6(CO)13(μ-CO)6(μ-dppm)2] 2 and [Os4Pd6(CO)8(μ-CO)8(μ-dppm)2] 3 in low yield, while the reaction of [Os3(μ5-C)(CO)15] with [Pd2(μ-dppm)2Cl2] afforded [Os5Pd4(μ6-C)(CO)12(μ-CO)3(μ-dppm)2] 4 and [Os5(μ5-C)(CO)13(μ-dppm)] 5 in moderate yields. The molecular structures of clusters 3 and 4 have been determined.",

author = "Hui, {Janesse Wing Sze} and Wong, {Wing Tak}",

year = "1998",

month = jun,

day = "21",

language = "English",

pages = "2065--2070",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "12",

}

Syntheses and characterization of high-nuclearity osmium-palladium mixed-metal carbonyl clusters; molecular structures of [Os₄Pd₆(CO)₈-(μ-CO)₅(μ₃-CO)₃(μ-dppm)₂]·0.5C₆H₁₄and [Os₅Pd₄(μ₆-C)(CO)₁₂-(μ-CO)₃(μ-dppm) ... / Hui, Janesse Wing Sze; Wong, Wing Tak.
In: Journal of the Chemical Society - Dalton Transactions, No. 12, 21.06.1998, p. 2065-2070.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Syntheses and characterization of high-nuclearity osmium-palladium mixed-metal carbonyl clusters; molecular structures of [Os4Pd6(CO)8-(μ-CO)5(μ3-CO)3(μ-dppm)2]·0.5C6H14and [Os5Pd4(μ6-C)(CO)12-(μ-CO)3(μ-dppm) ...

AU - Hui, Janesse Wing Sze

AU - Wong, Wing Tak

PY - 1998/6/21

Y1 - 1998/6/21

N2 - Title full: Syntheses and characterization of high-nuclearity osmium-palladium mixed-metal carbonyl clusters; molecular structures of [Os4Pd6(CO)8-(μ-CO)5(μ3-CO)3(μ-dppm)2]·0.5C6H14and [Os5Pd4(μ6-C)(CO)12-(μ-CO)3(μ-dppm)2]·CH2Cl2. Treatment of [Os3(CO)10(μ-H)2] with [Pd2(μ-dppm)2Cl2] afforded the novel high-nuclearity osmium-palladium mixed-metal carbonyl clusters [Os5Pd6(CO)13(μ-CO)5(μ-H)2(μ-dppm)2] 1, [Os5Pd6(CO)13(μ-CO)6(μ-dppm)2] 2 and [Os4Pd6(CO)8(μ-CO)8(μ-dppm)2] 3 in low yield, while the reaction of [Os3(μ5-C)(CO)15] with [Pd2(μ-dppm)2Cl2] afforded [Os5Pd4(μ6-C)(CO)12(μ-CO)3(μ-dppm)2] 4 and [Os5(μ5-C)(CO)13(μ-dppm)] 5 in moderate yields. The molecular structures of clusters 3 and 4 have been determined.

AB - Title full: Syntheses and characterization of high-nuclearity osmium-palladium mixed-metal carbonyl clusters; molecular structures of [Os4Pd6(CO)8-(μ-CO)5(μ3-CO)3(μ-dppm)2]·0.5C6H14and [Os5Pd4(μ6-C)(CO)12-(μ-CO)3(μ-dppm)2]·CH2Cl2. Treatment of [Os3(CO)10(μ-H)2] with [Pd2(μ-dppm)2Cl2] afforded the novel high-nuclearity osmium-palladium mixed-metal carbonyl clusters [Os5Pd6(CO)13(μ-CO)5(μ-H)2(μ-dppm)2] 1, [Os5Pd6(CO)13(μ-CO)6(μ-dppm)2] 2 and [Os4Pd6(CO)8(μ-CO)8(μ-dppm)2] 3 in low yield, while the reaction of [Os3(μ5-C)(CO)15] with [Pd2(μ-dppm)2Cl2] afforded [Os5Pd4(μ6-C)(CO)12(μ-CO)3(μ-dppm)2] 4 and [Os5(μ5-C)(CO)13(μ-dppm)] 5 in moderate yields. The molecular structures of clusters 3 and 4 have been determined.

UR - http://www.scopus.com/inward/record.url?scp=33751526122&partnerID=8YFLogxK

M3 - Journal article

SN - 1472-7773

SP - 2065

EP - 2070

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 12