Sustainability metrics of pretreatment processes in a waste derived lignocellulosic biomass biorefinery

Excessive utilization of fossil fuels has resulted in serious concerns about climate change. Integrating biorefinery technology to convert waste-derived-lignocellulosic biomass into biofuels and biopolymers has become an emerging topic toward our sustainable future. Pretreatment to fractionate the building block chemicals from the biomass is a crucial unit operation to ease the downstream processes in biorefinery. However, application of solvents and chemicals in the process can create many operational and environmental challenges in sensitive areas like highly populated cities. To shed light on how to determine a green biorefinery, this study presents the sustainability metrics of various pretreatment techniques and their operational risks during urbanization. The proposed green indexes include fractionation outputs, chemical recyclability, operational profile, and safety factors. In line with the design principles of lignin valorization, the issue of urban biomass and water-and-energy nexus are addressed to support future development and application of urban biorefinery for municipal waste management.