Superior energy storage BaTiO3-based amorphous dielectric film with polymorphic hexagonal and cubic nanostructures

Xuewen Jiang; Jiahao Lv; Zibin Chen; Zhonghui Shen; Jian Wang; Zhao Deng; Minghe Cao; Zhonghua Yao; Shujun Zhang; Hanxing Liu; Hua Hao

doi:10.1016/j.cej.2021.133447

Superior energy storage BaTiO₃-based amorphous dielectric film with polymorphic hexagonal and cubic nanostructures

Xuewen Jiang, Jiahao Lv, Zibin Chen, Zhonghui Shen, Jian Wang, Zhao Deng, Minghe Cao, Zhonghua Yao, Shujun Zhang, Hanxing Liu, Hua Hao

Research output: Journal article publication › Journal article › Academic research › peer-review

10 Citations (Scopus)

Abstract

An effective route to improve the energy storage performance by constructing polymorphic nanostructures in (1-x)BaTiO₃-xBi(Zn_1/2Zr_1/2)O₃ (BT-BZZ) films was proposed. The finite element simulation method was used to simulate the impacts of amorphous/crystalline phase and volume fraction on the electric field and polarization distributions. Together with the experimental observation, it is confirmed that an appropriate amorphous/crystalline structure volume fraction is conducive to the energy storage properties. Of particular significance is that Mn dopant in the 0.94BT-0.06BZZ films induces hexagonal BT phase with higher polarization compared with that of cubic phase, leading to a high energy density of 85 J/cm³ and greatly improved energy efficiency of 84% in 3Mn-0.94BT-0.06BZZ film. The existence of the amorphous structure and local polymorphic hexagonal/cubic nanostructures is confirmed by the aberration-corrected scanning transmission electron microscopy, which synergistically contribute to the greatly enhanced energy storage properties, providing a new design paradigm for high performance dielectric materials.

Original language	English
Article number	133447
Journal	Chemical Engineering Journal
Volume	431
Issue number	4
DOIs	https://doi.org/10.1016/j.cej.2021.133447
Publication status	Published - 1 Mar 2022
Externally published	Yes

Keywords

Amorphous structure
BaTiO-based
Dielectric film
Energy storage property
Nanocrystalline

ASJC Scopus subject areas

Chemistry(all)
Environmental Chemistry
Chemical Engineering(all)
Industrial and Manufacturing Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

More information

10.1016/j.cej.2021.133447

Cite this

@article{39f6b6ae55014df7a4ee651a5ba25e85,

title = "Superior energy storage BaTiO3-based amorphous dielectric film with polymorphic hexagonal and cubic nanostructures",

abstract = "An effective route to improve the energy storage performance by constructing polymorphic nanostructures in (1-x)BaTiO3-xBi(Zn1/2Zr1/2)O3 (BT-BZZ) films was proposed. The finite element simulation method was used to simulate the impacts of amorphous/crystalline phase and volume fraction on the electric field and polarization distributions. Together with the experimental observation, it is confirmed that an appropriate amorphous/crystalline structure volume fraction is conducive to the energy storage properties. Of particular significance is that Mn dopant in the 0.94BT-0.06BZZ films induces hexagonal BT phase with higher polarization compared with that of cubic phase, leading to a high energy density of 85 J/cm3 and greatly improved energy efficiency of 84% in 3Mn-0.94BT-0.06BZZ film. The existence of the amorphous structure and local polymorphic hexagonal/cubic nanostructures is confirmed by the aberration-corrected scanning transmission electron microscopy, which synergistically contribute to the greatly enhanced energy storage properties, providing a new design paradigm for high performance dielectric materials.",

keywords = "Amorphous structure, BaTiO-based, Dielectric film, Energy storage property, Nanocrystalline",

author = "Xuewen Jiang and Jiahao Lv and Zibin Chen and Zhonghui Shen and Jian Wang and Zhao Deng and Minghe Cao and Zhonghua Yao and Shujun Zhang and Hanxing Liu and Hua Hao",

note = "Funding Information: This work was supported by Major Program of the Natural Science Foundation of China (Grant No. 51790490 ), Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory (Grant No. XHT2020-011 ), Natural Science Foundation of China (Grant No. 51872213 ), the Major Research Plan of Natural Science Foundation of China (Grant No. 92066103 ), Natural Science Foundation of China (Grant No. 52002300 ) and Self-determined and Innovative Research Funds of SKLWUT ( 2021-PY-4 ). Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",

year = "2022",

month = mar,

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doi = "10.1016/j.cej.2021.133447",

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TY - JOUR

T1 - Superior energy storage BaTiO3-based amorphous dielectric film with polymorphic hexagonal and cubic nanostructures

AU - Jiang, Xuewen

AU - Lv, Jiahao

AU - Chen, Zibin

AU - Shen, Zhonghui

AU - Wang, Jian

AU - Deng, Zhao

AU - Cao, Minghe

AU - Yao, Zhonghua

AU - Zhang, Shujun

AU - Liu, Hanxing

AU - Hao, Hua

N1 - Funding Information: This work was supported by Major Program of the Natural Science Foundation of China (Grant No. 51790490 ), Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory (Grant No. XHT2020-011 ), Natural Science Foundation of China (Grant No. 51872213 ), the Major Research Plan of Natural Science Foundation of China (Grant No. 92066103 ), Natural Science Foundation of China (Grant No. 52002300 ) and Self-determined and Innovative Research Funds of SKLWUT ( 2021-PY-4 ). Publisher Copyright: © 2021 Elsevier B.V.

PY - 2022/3/1

Y1 - 2022/3/1

N2 - An effective route to improve the energy storage performance by constructing polymorphic nanostructures in (1-x)BaTiO3-xBi(Zn1/2Zr1/2)O3 (BT-BZZ) films was proposed. The finite element simulation method was used to simulate the impacts of amorphous/crystalline phase and volume fraction on the electric field and polarization distributions. Together with the experimental observation, it is confirmed that an appropriate amorphous/crystalline structure volume fraction is conducive to the energy storage properties. Of particular significance is that Mn dopant in the 0.94BT-0.06BZZ films induces hexagonal BT phase with higher polarization compared with that of cubic phase, leading to a high energy density of 85 J/cm3 and greatly improved energy efficiency of 84% in 3Mn-0.94BT-0.06BZZ film. The existence of the amorphous structure and local polymorphic hexagonal/cubic nanostructures is confirmed by the aberration-corrected scanning transmission electron microscopy, which synergistically contribute to the greatly enhanced energy storage properties, providing a new design paradigm for high performance dielectric materials.

AB - An effective route to improve the energy storage performance by constructing polymorphic nanostructures in (1-x)BaTiO3-xBi(Zn1/2Zr1/2)O3 (BT-BZZ) films was proposed. The finite element simulation method was used to simulate the impacts of amorphous/crystalline phase and volume fraction on the electric field and polarization distributions. Together with the experimental observation, it is confirmed that an appropriate amorphous/crystalline structure volume fraction is conducive to the energy storage properties. Of particular significance is that Mn dopant in the 0.94BT-0.06BZZ films induces hexagonal BT phase with higher polarization compared with that of cubic phase, leading to a high energy density of 85 J/cm3 and greatly improved energy efficiency of 84% in 3Mn-0.94BT-0.06BZZ film. The existence of the amorphous structure and local polymorphic hexagonal/cubic nanostructures is confirmed by the aberration-corrected scanning transmission electron microscopy, which synergistically contribute to the greatly enhanced energy storage properties, providing a new design paradigm for high performance dielectric materials.

KW - Amorphous structure

KW - BaTiO-based

KW - Dielectric film

KW - Energy storage property

KW - Nanocrystalline

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DO - 10.1016/j.cej.2021.133447

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