Sub-micrometer-sized LiMn1.5Ni0.5O4spheres as high rate cathode materials for long-life lithium ion batteries

Yunxian Qian, Yuanfu Deng, Zhicong Shi, Yubo Zhou, Quanchao Zhuang, Guohua Chen

Research output: Journal article publicationJournal articleAcademic researchpeer-review

39 Citations (Scopus)

Abstract

Spinel LiMn1.5Ni0.5O4(LMNO) sub-micrometer-sized spheres were prepared in one step using porous MnCO3microspheres as a self-supporting template. The LMNO spheres were characterized by XRD, SEM and TEM. The obtained LMNO was in a well-crystallized cubic phase with little impurity. It showed high rate capability and excellent cycling stability as a cathode material for lithium ion batteries. Initial discharge capacities of 122.0, 120.3, 119.5 and 112.1 mAh g- 1were found at 2, 3, 5 and 10C respectively with 1C being 146.7 mA g- 1. Their capacity retentions are 92, 91, 82 and 79% respectively after 500 cycles. The as-prepared LMNO is a promising cathode material for high power and long-life lithium ion batteries.
Original languageEnglish
Pages (from-to)92-95
Number of pages4
JournalElectrochemistry Communications
Volume27
DOIs
Publication statusPublished - 1 Feb 2013
Externally publishedYes

Keywords

  • Cathode
  • High capacity retention
  • LiMn Ni O spheres 1.5 0.5 4
  • Self-supporting template synthesis

ASJC Scopus subject areas

  • Electrochemistry

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