Sub-micrometer-sized LiMn1.5Ni0.5O4spheres as high rate cathode materials for long-life lithium ion batteries

Yunxian Qian; Yuanfu Deng; Zhicong Shi; Yubo Zhou; Quanchao Zhuang; Guohua Chen

doi:10.1016/j.elecom.2012.11.004

Sub-micrometer-sized LiMn_1.5Ni_0.5O₄spheres as high rate cathode materials for long-life lithium ion batteries

Yunxian Qian, Yuanfu Deng, Zhicong Shi, Yubo Zhou, Quanchao Zhuang, Guohua Chen

Research output: Journal article publication › Journal article › Academic research › peer-review

43 Citations (Scopus)

Abstract

Spinel LiMn1.5Ni0.5O4(LMNO) sub-micrometer-sized spheres were prepared in one step using porous MnCO3microspheres as a self-supporting template. The LMNO spheres were characterized by XRD, SEM and TEM. The obtained LMNO was in a well-crystallized cubic phase with little impurity. It showed high rate capability and excellent cycling stability as a cathode material for lithium ion batteries. Initial discharge capacities of 122.0, 120.3, 119.5 and 112.1 mAh g- 1were found at 2, 3, 5 and 10C respectively with 1C being 146.7 mA g- 1. Their capacity retentions are 92, 91, 82 and 79% respectively after 500 cycles. The as-prepared LMNO is a promising cathode material for high power and long-life lithium ion batteries.

Original language	English
Pages (from-to)	92-95
Number of pages	4
Journal	Electrochemistry Communications
Volume	27
DOIs	https://doi.org/10.1016/j.elecom.2012.11.004
Publication status	Published - 1 Feb 2013
Externally published	Yes

Keywords

Cathode
High capacity retention
LiMn Ni O spheres 1.5 0.5 4
Self-supporting template synthesis

ASJC Scopus subject areas

Electrochemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

More information

10.1016/j.elecom.2012.11.004

Cite this

@article{be158bd6d2b34496a562df1759f8f987,

title = "Sub-micrometer-sized LiMn1.5Ni0.5O4spheres as high rate cathode materials for long-life lithium ion batteries",

abstract = "Spinel LiMn1.5Ni0.5O4(LMNO) sub-micrometer-sized spheres were prepared in one step using porous MnCO3microspheres as a self-supporting template. The LMNO spheres were characterized by XRD, SEM and TEM. The obtained LMNO was in a well-crystallized cubic phase with little impurity. It showed high rate capability and excellent cycling stability as a cathode material for lithium ion batteries. Initial discharge capacities of 122.0, 120.3, 119.5 and 112.1 mAh g- 1were found at 2, 3, 5 and 10C respectively with 1C being 146.7 mA g- 1. Their capacity retentions are 92, 91, 82 and 79% respectively after 500 cycles. The as-prepared LMNO is a promising cathode material for high power and long-life lithium ion batteries.",

keywords = "Cathode, High capacity retention, LiMn Ni O spheres 1.5 0.5 4, Self-supporting template synthesis",

author = "Yunxian Qian and Yuanfu Deng and Zhicong Shi and Yubo Zhou and Quanchao Zhuang and Guohua Chen",

year = "2013",

month = feb,

day = "1",

doi = "10.1016/j.elecom.2012.11.004",

language = "English",

volume = "27",

pages = "92--95",

journal = "Electrochemistry Communications",

issn = "1388-2481",

publisher = "Elsevier Inc.",

}

TY - JOUR

T1 - Sub-micrometer-sized LiMn1.5Ni0.5O4spheres as high rate cathode materials for long-life lithium ion batteries

AU - Qian, Yunxian

AU - Deng, Yuanfu

AU - Shi, Zhicong

AU - Zhou, Yubo

AU - Zhuang, Quanchao

AU - Chen, Guohua

PY - 2013/2/1

Y1 - 2013/2/1

N2 - Spinel LiMn1.5Ni0.5O4(LMNO) sub-micrometer-sized spheres were prepared in one step using porous MnCO3microspheres as a self-supporting template. The LMNO spheres were characterized by XRD, SEM and TEM. The obtained LMNO was in a well-crystallized cubic phase with little impurity. It showed high rate capability and excellent cycling stability as a cathode material for lithium ion batteries. Initial discharge capacities of 122.0, 120.3, 119.5 and 112.1 mAh g- 1were found at 2, 3, 5 and 10C respectively with 1C being 146.7 mA g- 1. Their capacity retentions are 92, 91, 82 and 79% respectively after 500 cycles. The as-prepared LMNO is a promising cathode material for high power and long-life lithium ion batteries.

AB - Spinel LiMn1.5Ni0.5O4(LMNO) sub-micrometer-sized spheres were prepared in one step using porous MnCO3microspheres as a self-supporting template. The LMNO spheres were characterized by XRD, SEM and TEM. The obtained LMNO was in a well-crystallized cubic phase with little impurity. It showed high rate capability and excellent cycling stability as a cathode material for lithium ion batteries. Initial discharge capacities of 122.0, 120.3, 119.5 and 112.1 mAh g- 1were found at 2, 3, 5 and 10C respectively with 1C being 146.7 mA g- 1. Their capacity retentions are 92, 91, 82 and 79% respectively after 500 cycles. The as-prepared LMNO is a promising cathode material for high power and long-life lithium ion batteries.

KW - Cathode

KW - High capacity retention

KW - LiMn Ni O spheres 1.5 0.5 4

KW - Self-supporting template synthesis

UR - http://www.scopus.com/inward/record.url?scp=84870310023&partnerID=8YFLogxK

U2 - 10.1016/j.elecom.2012.11.004

DO - 10.1016/j.elecom.2012.11.004

M3 - Journal article

SN - 1388-2481

VL - 27

SP - 92

EP - 95

JO - Electrochemistry Communications

JF - Electrochemistry Communications

ER -