Structure, electrical properties and temperature characteristics of Bi 0.5Na0.5TiO3-Bi0.5K 0.5TiO3-Bi0.5Li0.5TiO3 lead-free piezoelectric ceramics

Dunmin Lin, Qiaoji Zheng, Chenggang Xu, Kin Wing Kwok

Research output: Journal article publicationJournal articleAcademic researchpeer-review

53 Citations (Scopus)


(1-x-y)Bi0.5Na0.5TiO3-xBi 0.5K0.5TiO3- yBi0.5Li 0.5TiO3 lead-free piezoelectric ceramics have been prepared by an ordinary sintering technique, and their structure, electrical properties, and temperature characteristics have been studied systematically. The ceramics can be well-sintered at 1050-1150∈°C. The increase in K+ concentration decreases the grain-growth rate and promotes the formation of grains with a cubic shape, while the addition of Li+ decreases greatly the sintering temperature and assists in the densification of BNT-based ceramics. The results of XRD diffraction show that K+ and Li+ diffuse into the Bi0.5Na0.5TiO3 lattices to form a solid solution with a pure perovskite structure. As x increases from 0.05 to 0.50, the ceramics transform gradually from rhombohedral phase to tetragonal phase and consequently a morphotropic phase boundary (MPB) is formed at 0.15 ≤ x ≤ 0.25. The concentration y of Li+ has no obvious influence on the crystal structure of the ceramics. Compared with pure Bi0.5Na0.5TiO3, the partial substitution of K+ and Li+ for Na+ lowers greatly the coercive field E c and increases the remanent polarization P r of the ceramics. Because of the MPB, lower E c and large P r, the piezoelectricity of the ceramics is improved significantly. For the ceramics with the compositions near the MPB (x=0.15-0.25 and y=0.05-0.10), the piezoelectric properties become optimum: piezoelectric coefficient d 33=147-231 pC/N and planar electromechanical coupling factor k P=20.2-41.0%. In addition, the ceramics exhibit relaxor characteristic, which probably results from the cation disordering in the 12-fold coordination sites. The depolarization temperature T d shows a strong dependence on the concentration x of K+ and reaches the lowest values at the MPB. The temperature dependences of the ferroelectric and dielectric properties at high temperatures may imply that the ceramics may contain both the polar and non-polar regions at temperatures above T d.
Original languageEnglish
Pages (from-to)549-558
Number of pages10
JournalApplied Physics A: Materials Science and Processing
Issue number2
Publication statusPublished - 1 Nov 2008

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science


Dive into the research topics of 'Structure, electrical properties and temperature characteristics of Bi 0.5Na0.5TiO3-Bi0.5K 0.5TiO3-Bi0.5Li0.5TiO3 lead-free piezoelectric ceramics'. Together they form a unique fingerprint.

Cite this