Structural characterization of shielded isomeric europium complexes with metal-metal contact

Ga Lai Law, Ka Leung Wong, Yang Yi Yang, Qiao Yuan Yi, Guohua Jia, Wing Tak Wong, Peter A. Tanner

Research output: Journal article publicationJournal articleAcademic researchpeer-review

42 Citations (Scopus)

Abstract

New luminescent isomeric europium(III) complexes with carboxylic carbonyl group coordination (I and II) have been prepared by solvothermal synthesis using the ligand 2,2′-bipyridine-4,4′-dicarboxylic acid (bpdc), with the nonradiatively shielded Eu3+coordination sphere completed by dimethyl sulfoxide ligands. The room temperature IR spectra and Eu3+luminescence spectra do not provide a definitive distinction between I and II, but low-temperature luminescence can give a clear identification.
Original languageEnglish
Pages (from-to)9754-9759
Number of pages6
JournalInorganic Chemistry
Volume46
Issue number23
DOIs
Publication statusPublished - 12 Nov 2007
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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