Abstract
Chiral C2-symmetric quaterpyridine L reacts with [Pd(η3-C3H5)Cl]2 to form a chiral single-stranded helical binuclear palladium complex of formula [Pd 2(η3-C3H5)2(L)] 2+; the complex can efficiently catalyze allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate with enantioselectivity up to 85%.
| Original language | English |
|---|---|
| Pages (from-to) | 4841-4843 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Issue number | 46 |
| DOIs | |
| Publication status | Published - 29 Nov 2006 |
| Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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