Abstract
In this study, spectrally selective coating with improved near-infrared shielding property was fabricated by direct spray technique using the Cs0.33WO3 and Sb-doped SnO2 as composite filler. The effect of Cs/W molar ratio on phase composition, crystal structure, morphology, chemical state and optical property was investigated. The results reveal that the Cs/W molar ratio has a significant influence in promoting the form of hexagonal crystal structure, which is beneficial to improve spectral selectivity. Especially, when the Cs/W molar ratio was 0.375, the as-synthesized Cs0.33WO3 product demonstrated the desired phase composition and W5+ generation. Furthermore, the spectrally selective coating prepared by the dispersion with 10 wt% composite filler combined with Cs0.33WO3 and Sb-doped SnO2 presented optimal optical performance. The excellent near-infrared shielding performance of the spectrally selective coating indicates great potential in the field of energy-efficient glazing.
Original language | English |
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Pages (from-to) | 18991-18997 |
Number of pages | 7 |
Journal | Ceramics International |
Volume | 47 |
Issue number | 13 |
DOIs | |
Publication status | Published - 1 Jul 2021 |
Keywords
- CsWO
- Energy-efficient glazing
- Sb-doped SnO, near-infrared shielding
- Spectrally selective coating
- Spray fabrication
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Process Chemistry and Technology
- Surfaces, Coatings and Films
- Materials Chemistry