Solid State Synthesis and Structural Characterization of Binuclear Cu(I)-SbPh3 Complex [Cu (SbPh3)2I]2

Qian Feng Zhang; Dong Xiang Zeng; Xin Quan Xin; Wing Tak Wong

Solid State Synthesis and Structural Characterization of Binuclear Cu(I)-SbPh₃ Complex [Cu (SbPh₃)₂I]₂

Qian Feng Zhang
, Dong Xiang Zeng
, Xin Quan Xin
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

Abstract

Dimeric complex [Cu(SbPh3)2I]2 has been synthesized by a solid state reaction at a low heating temperature and its crystal structure has been analyzed by X-ray crystallography. The crystal is monoclinic, space group P21/a (#14), a = 20.436(5), b=14.125(3), c=24. 683(3) Å, β=110. 67(1)°, Z=4, V=6666(2) Å3; C72H60Sb4I2Cu2, Mr= 1792, Dr= 1.787 g • cm-3, μ(.MoKα) = 31.88 cm-1, F(000) = 3440, R=0. 038 and Rω=0. 043 for 5632 observed reflections (I≥3. 0σ(I)) and 361 refined parameters. The result reveals the copper and the bridging iodide atoms form an approximately planar rhomboid array. Effects of the bulkiness of the ligands upon the structures of the analogous complexes are discussed.

Original language	English
Pages (from-to)	356-360
Number of pages	5
Journal	Jiegou Huaxue
Volume	18
Issue number	5
Publication status	Published - 1 Dec 1999
Externally published	Yes

Keywords

Crystal structure
Cu(I)-SbPh complex 3
IR spectrum
Solid state synthesis

ASJC Scopus subject areas

General Chemistry

Cite this

@article{e60559b2f8ca45a8b0d395f12b9906f8,

title = "Solid State Synthesis and Structural Characterization of Binuclear Cu(I)-SbPh3 Complex [Cu (SbPh3)2I]2",

abstract = "Dimeric complex [Cu(SbPh3)2I]2 has been synthesized by a solid state reaction at a low heating temperature and its crystal structure has been analyzed by X-ray crystallography. The crystal is monoclinic, space group P21/a (\#14), a = 20.436(5), b=14.125(3), c=24. 683(3) {\AA}, β=110. 67(1)°, Z=4, V=6666(2) {\AA}3; C72H60Sb4I2Cu2, Mr= 1792, Dr= 1.787 g • cm-3, μ(.MoKα) = 31.88 cm-1, F(000) = 3440, R=0. 038 and Rω=0. 043 for 5632 observed reflections (I≥3. 0σ(I)) and 361 refined parameters. The result reveals the copper and the bridging iodide atoms form an approximately planar rhomboid array. Effects of the bulkiness of the ligands upon the structures of the analogous complexes are discussed.",

keywords = "Crystal structure, Cu(I)-SbPh complex 3, IR spectrum, Solid state synthesis",

author = "Zhang, \{Qian Feng\} and Zeng, \{Dong Xiang\} and Xin, \{Xin Quan\} and Wong, \{Wing Tak\}",

year = "1999",

month = dec,

day = "1",

language = "English",

volume = "18",

pages = "356--360",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "5",

}

TY - JOUR

T1 - Solid State Synthesis and Structural Characterization of Binuclear Cu(I)-SbPh3 Complex [Cu (SbPh3)2I]2

AU - Zhang, Qian Feng

AU - Zeng, Dong Xiang

AU - Xin, Xin Quan

AU - Wong, Wing Tak

PY - 1999/12/1

Y1 - 1999/12/1

N2 - Dimeric complex [Cu(SbPh3)2I]2 has been synthesized by a solid state reaction at a low heating temperature and its crystal structure has been analyzed by X-ray crystallography. The crystal is monoclinic, space group P21/a (#14), a = 20.436(5), b=14.125(3), c=24. 683(3) Å, β=110. 67(1)°, Z=4, V=6666(2) Å3; C72H60Sb4I2Cu2, Mr= 1792, Dr= 1.787 g • cm-3, μ(.MoKα) = 31.88 cm-1, F(000) = 3440, R=0. 038 and Rω=0. 043 for 5632 observed reflections (I≥3. 0σ(I)) and 361 refined parameters. The result reveals the copper and the bridging iodide atoms form an approximately planar rhomboid array. Effects of the bulkiness of the ligands upon the structures of the analogous complexes are discussed.

AB - Dimeric complex [Cu(SbPh3)2I]2 has been synthesized by a solid state reaction at a low heating temperature and its crystal structure has been analyzed by X-ray crystallography. The crystal is monoclinic, space group P21/a (#14), a = 20.436(5), b=14.125(3), c=24. 683(3) Å, β=110. 67(1)°, Z=4, V=6666(2) Å3; C72H60Sb4I2Cu2, Mr= 1792, Dr= 1.787 g • cm-3, μ(.MoKα) = 31.88 cm-1, F(000) = 3440, R=0. 038 and Rω=0. 043 for 5632 observed reflections (I≥3. 0σ(I)) and 361 refined parameters. The result reveals the copper and the bridging iodide atoms form an approximately planar rhomboid array. Effects of the bulkiness of the ligands upon the structures of the analogous complexes are discussed.

KW - Crystal structure

KW - Cu(I)-SbPh complex 3

KW - IR spectrum

KW - Solid state synthesis

UR - https://www.scopus.com/pages/publications/0347083201

M3 - Journal article

SN - 0254-5861

VL - 18

SP - 356

EP - 360

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 5

ER -

Solid State Synthesis and Structural Characterization of Binuclear Cu(I)-SbPh₃ Complex [Cu (SbPh₃)₂I]₂

Abstract

Keywords

ASJC Scopus subject areas

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