Solid State Synthesis and Structural Characterization of Binuclear Cu(I)-SbPh3 Complex [Cu (SbPh3)2I]2

Qian Feng Zhang, Dong Xiang Zeng, Xin Quan Xin, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

2 Citations (Scopus)

Abstract

Dimeric complex [Cu(SbPh3)2I]2 has been synthesized by a solid state reaction at a low heating temperature and its crystal structure has been analyzed by X-ray crystallography. The crystal is monoclinic, space group P21/a (#14), a = 20.436(5), b=14.125(3), c=24. 683(3) Å, β=110. 67(1)°, Z=4, V=6666(2) Å3; C72H60Sb4I2Cu2, Mr= 1792, Dr= 1.787 g • cm-3, μ(.MoKα) = 31.88 cm-1, F(000) = 3440, R=0. 038 and Rω=0. 043 for 5632 observed reflections (I≥3. 0σ(I)) and 361 refined parameters. The result reveals the copper and the bridging iodide atoms form an approximately planar rhomboid array. Effects of the bulkiness of the ligands upon the structures of the analogous complexes are discussed.
Original languageEnglish
Pages (from-to)356-360
Number of pages5
JournalJiegou Huaxue
Volume18
Issue number5
Publication statusPublished - 1 Dec 1999
Externally publishedYes

Keywords

  • Crystal structure
  • Cu(I)-SbPh complex 3
  • IR spectrum
  • Solid state synthesis

ASJC Scopus subject areas

  • Chemistry(all)

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