Silver(i)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions

Vanessa Kar Yan Lo; Cong Ying Zhou; Man Kin Wong; Chi Ming Che

doi:10.1039/b914516h

Silver(i)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions

Vanessa Kar Yan Lo, Cong Ying Zhou, Man Kin Wong, Chi Ming Che

Research output: Journal article publication › Journal article › Academic research › peer-review

114 Citations (Scopus)

Abstract

Silver(i) salts mediated stereospecific transformation of optically active propargylamines to axially chiral allenes with excellent enantioselectivities (17 examples with 96-99% ee; one substrate with 91% ee) without subsequent racemization.

Original language	English
Pages (from-to)	213-215
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	2
DOIs	https://doi.org/10.1039/b914516h
Publication status	Published - 5 Feb 2010

ASJC Scopus subject areas

Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Catalysis
General Chemistry

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10.1039/b914516h

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title = "Silver(i)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions",

abstract = "Silver(i) salts mediated stereospecific transformation of optically active propargylamines to axially chiral allenes with excellent enantioselectivities (17 examples with 96-99% ee; one substrate with 91% ee) without subsequent racemization.",

author = "Lo, {Vanessa Kar Yan} and Zhou, {Cong Ying} and Wong, {Man Kin} and Che, {Chi Ming}",

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AU - Lo, Vanessa Kar Yan

AU - Zhou, Cong Ying

AU - Wong, Man Kin

AU - Che, Chi Ming

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AB - Silver(i) salts mediated stereospecific transformation of optically active propargylamines to axially chiral allenes with excellent enantioselectivities (17 examples with 96-99% ee; one substrate with 91% ee) without subsequent racemization.

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DO - 10.1039/b914516h

M3 - Journal article

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JF - Chemical Communications

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Silver(i)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions

Abstract

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