Silicon-encapsulated hollow carbon nanofiber networks as binder-free anodes for lithium ion battery

Ding Nan, Zheng Hong Huang, Ruitao Lv, Yuxiao Lin, Lu Yang, Xiaoliang Yu, Ling Ye, Wanci Shen, Hongyu Sun, Feiyu Kang

Research output: Journal article publicationJournal articleAcademic researchpeer-review

10 Citations (Scopus)

Abstract

Silicon-encapsulated hollow carbon nanofiber networks with ample space around the Si nanoparticles (hollow Si/C composites) were successfully synthesized by dip-coating phenolic resin onto the surface of electrospun Si/PVA nanofibers along with the subsequent solidification and carbonization. More importantly, the structure and Si content of hollow Si/C composite nanofibers can be effectively tuned by merely varying the concentration of dip solution. As-synthesized hollow Si/C composites show excellent electrochemical performance when they are used as binder-free anodes for Li-ion batteries (LIBs). In particular, when the concentration of resol/ethanol solution is 3.0%, the product exhibits a large capacity of 841 mAh g-1 in the first cycle, prominent cycling stability, and good rate capability. The discharge capacity retention of it was 90%, with 745 mAh g-1 after 50 cycles. The results demonstrate that the hollow Si/C composites are very promising as alternative anode candidates for high-performance LIBs.

Original languageEnglish
Article number139639
JournalJournal of Nanomaterials
Volume2014
DOIs
Publication statusPublished - 2014
Externally publishedYes

ASJC Scopus subject areas

  • Materials Science(all)

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