Shape memory investigation of α-Keratin Fibers as Multi-Coupled stimuli of responsive Smart Materials

Xueliang Xiao, Jinlian Hu, Xiaoting Gui, Kun Qian

Research output: Journal article publicationJournal articleAcademic researchpeer-review

16 Citations (Scopus)

Abstract

Licensee MDPI, Basel, Switzerland. Like the water responsive shape memory (SM) effect of β-keratin bird feathers, α-keratin hairs either existing broadly in nature are found responsive to many types of coupled stimuli in SM behaviors. In this article, α-keratin hairs were investigated for the combined stimuli of thermo-solvent, solvent-solvent, and UV (radiation)-reductant sensitive SM abilities. The related netpoints and switches from the hair molecular networks were identified. The experimental results showed that α-keratin hairs manifested a higher ability of shape fixation under thermal stimulus followed with the stimuli of solvent and UV-radiation. Shape recovery from the hair with a temporarily fixed shape showed a higher recovery ability using solvent than the stimuli of heat and UV-radiation. The effects of coupled stimuli on hair's shape fixation and recovery and on variations of the crystal, disulfide, and hydrogen bonds were studied systematically. A structural network model was thereafter proposed to interpret the multi-coupled stimuli sensitive SM of α-keratin hair. This original study is expected to provide inspiration for exploring other natural fibers to reveal related smart functions and for making more types of remarkable adapted synthetic materials.
Original languageEnglish
Article number87
JournalPolymers
Volume9
Issue number3
DOIs
Publication statusPublished - 1 Jan 2017

Keywords

  • Coupled stimuli
  • Network model
  • Shape memory
  • α-keratin fiber

ASJC Scopus subject areas

  • Chemistry(all)
  • Polymers and Plastics

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