TY - JOUR
T1 - Self-Catalyzed Growth of Co, N-Codoped CNTs on Carbon-Encased CoSx Surface
T2 - A Noble-Metal-Free Bifunctional Oxygen Electrocatalyst for Flexible Solid Zn–Air Batteries
AU - Lu, Qian
AU - Yu, Jie
AU - Zou, Xiaohong
AU - Liao, Kaiming
AU - Tan, Peng
AU - Zhou, Wei
AU - Ni, Meng
AU - Shao, Zongping
PY - 2019/9/1
Y1 - 2019/9/1
N2 - The self-catalyzed growth of nanostructures on material surfaces is one of the most time- and cost-effective ways to design multifunctional catalysts for a wide range of applications. Herein, the use of this technique to develop a multicomponent composite catalyst with CoSx core encapsulated in an ultrathin porous carbon shell entangled with Co, N-codoped carbon nanotubes is reported. The as-prepared catalyst has a superior catalytic activity for oxygen evolution and oxygen reduction reactions, an ultralow potential gap of 0.74 V, and outstanding durability, surpassing most previous reports. Such superiority is ascribed, in part, to the unique 3D electrode architecture of the composite, which is favorable for transporting oxygen species and electrons and creates a synergy between the components with different functionalities. Moreover, the flexible solid Zn–air battery assembled with such an air electrode shows a steady discharge voltage plateau of 1.25 V and a round-trip efficiency of 70% at 1 mA cm−2. This work presents a simple strategy to design highly efficient bifunctional oxygen electrocatalysts and may pave the way for the practical application of these materials in many energy conversion/storage devices.
AB - The self-catalyzed growth of nanostructures on material surfaces is one of the most time- and cost-effective ways to design multifunctional catalysts for a wide range of applications. Herein, the use of this technique to develop a multicomponent composite catalyst with CoSx core encapsulated in an ultrathin porous carbon shell entangled with Co, N-codoped carbon nanotubes is reported. The as-prepared catalyst has a superior catalytic activity for oxygen evolution and oxygen reduction reactions, an ultralow potential gap of 0.74 V, and outstanding durability, surpassing most previous reports. Such superiority is ascribed, in part, to the unique 3D electrode architecture of the composite, which is favorable for transporting oxygen species and electrons and creates a synergy between the components with different functionalities. Moreover, the flexible solid Zn–air battery assembled with such an air electrode shows a steady discharge voltage plateau of 1.25 V and a round-trip efficiency of 70% at 1 mA cm−2. This work presents a simple strategy to design highly efficient bifunctional oxygen electrocatalysts and may pave the way for the practical application of these materials in many energy conversion/storage devices.
KW - bifunctional electrocatalyst
KW - oxygen electrode
KW - self-catalyzed growth
KW - synergistic effect
KW - Zn–air battery
UR - http://www.scopus.com/inward/record.url?scp=85069899769&partnerID=8YFLogxK
U2 - 10.1002/adfm.201904481
DO - 10.1002/adfm.201904481
M3 - Journal article
AN - SCOPUS:85069899769
SN - 1616-301X
VL - 29
JO - Advanced Functional Materials
JF - Advanced Functional Materials
IS - 38
M1 - 1904481
ER -