Self-Catalyzed Growth of Co, N-Codoped CNTs on Carbon-Encased CoSx Surface: A Noble-Metal-Free Bifunctional Oxygen Electrocatalyst for Flexible Solid Zn–Air Batteries

Qian Lu, Jie Yu, Xiaohong Zou, Kaiming Liao, Peng Tan, Wei Zhou, Meng Ni, Zongping Shao

Research output: Journal article publicationJournal articleAcademic researchpeer-review

108 Citations (Scopus)

Abstract

The self-catalyzed growth of nanostructures on material surfaces is one of the most time- and cost-effective ways to design multifunctional catalysts for a wide range of applications. Herein, the use of this technique to develop a multicomponent composite catalyst with CoSx core encapsulated in an ultrathin porous carbon shell entangled with Co, N-codoped carbon nanotubes is reported. The as-prepared catalyst has a superior catalytic activity for oxygen evolution and oxygen reduction reactions, an ultralow potential gap of 0.74 V, and outstanding durability, surpassing most previous reports. Such superiority is ascribed, in part, to the unique 3D electrode architecture of the composite, which is favorable for transporting oxygen species and electrons and creates a synergy between the components with different functionalities. Moreover, the flexible solid Zn–air battery assembled with such an air electrode shows a steady discharge voltage plateau of 1.25 V and a round-trip efficiency of 70% at 1 mA cm−2. This work presents a simple strategy to design highly efficient bifunctional oxygen electrocatalysts and may pave the way for the practical application of these materials in many energy conversion/storage devices.

Original languageEnglish
Article number1904481
JournalAdvanced Functional Materials
Volume29
Issue number38
DOIs
Publication statusPublished - 1 Sep 2019

Keywords

  • bifunctional electrocatalyst
  • oxygen electrode
  • self-catalyzed growth
  • synergistic effect
  • Zn–air battery

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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