Ruthenium-catalyzed stereoselective intramolecular carbenoid C-H insertion for β- and γ-lactam formations by decomposition of α-diazoacetamides

Keyphrases

• Carbenoids 100%
• Stereoselectivity 100%
• Ruthenium Catalyst 100%
• C-H Insertion 100%
• Lactam Formation 100%
• Diazoacetate 100%
• Slow Addition 50%
• Ru-catalyzed 50%
• Excellent Yields 50%
• Lactams 50%
• Catalytic System 50%
• Inert Atmosphere 50%
• Carbenoid Insertion 50%
• Aromatic C-H Bonds 50%
• Stereoselective Cyclization 50%
• Diazo Compounds 50%
• P-cymene 50%
• Systems-based 50%
• Catalyzed Reaction 50%
• Percentage Yield 50%

Chemistry

• Ruthenium 100%
• formation 100%
• Lactam 100%
• Catalysis 33%
• Diazo Compound 33%
• Stereoselectivity 33%
• Inert Atmosphere 33%