Rhodium-catalyzed asymmetric hydroarylation of 3-pyrrolines giving 3-arylpyrrolidines: Protonation as a key step

Chau Ming So; Satoshi Kume; Tamio Hayashi

doi:10.1021/ja406169s

Rhodium-catalyzed asymmetric hydroarylation of 3-pyrrolines giving 3-arylpyrrolidines: Protonation as a key step

Chau Ming So, Satoshi Kume, Tamio Hayashi

Research output: Journal article publication › Journal article › Academic research › peer-review

59 Citations (Scopus)

Abstract

A hydroxorhodium complex coordinated with (R)-segphos was found to catalyze the hydroarylation of 3-pyrrolines with arylboroxines under neutral conditions to give 3-arylpyrrolidines with high enantioselectivity in high yields.

Original language	English
Pages (from-to)	10990-10993
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	30
DOIs	https://doi.org/10.1021/ja406169s
Publication status	Published - 31 Jul 2013
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja406169s

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title = "Rhodium-catalyzed asymmetric hydroarylation of 3-pyrrolines giving 3-arylpyrrolidines: Protonation as a key step",

abstract = "A hydroxorhodium complex coordinated with (R)-segphos was found to catalyze the hydroarylation of 3-pyrrolines with arylboroxines under neutral conditions to give 3-arylpyrrolidines with high enantioselectivity in high yields.",

author = "So, {Chau Ming} and Satoshi Kume and Tamio Hayashi",

year = "2013",

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AU - So, Chau Ming

AU - Kume, Satoshi

AU - Hayashi, Tamio

PY - 2013/7/31

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N2 - A hydroxorhodium complex coordinated with (R)-segphos was found to catalyze the hydroarylation of 3-pyrrolines with arylboroxines under neutral conditions to give 3-arylpyrrolidines with high enantioselectivity in high yields.

AB - A hydroxorhodium complex coordinated with (R)-segphos was found to catalyze the hydroarylation of 3-pyrrolines with arylboroxines under neutral conditions to give 3-arylpyrrolidines with high enantioselectivity in high yields.

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U2 - 10.1021/ja406169s

DO - 10.1021/ja406169s

M3 - Journal article

SN - 0002-7863

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SP - 10990

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 30

ER -

Rhodium-catalyzed asymmetric hydroarylation of 3-pyrrolines giving 3-arylpyrrolidines: Protonation as a key step

Abstract

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