Removal and recovery of Cr(VI) from wastewater by maghemite nanoparticles

Jing Hu, Guohua Chen, Irene M.C. Lo

Research output: Journal article publicationJournal articleAcademic researchpeer-review

825 Citations (Scopus)

Abstract

Hexavalent chromium existing in the effluent is a major concern for the metal-processing plant. In this study, a new method combining nanoparticle adsorption and magnetic separation was developed for the removal and recovery of Cr(VI) from wastewater. The nanoscale maghemite was synthesized, characterized, and evaluated as adsorbents of Cr(VI). Various factors influencing the adsorption of Cr(VI), e.g., pH, temperature, initial concentration, and coexisting common ions were studied. Adsorption reached equilibrium within 15 min and was independent of initial Cr concentration. The maximum adsorption occurred at pH 2.5. The adsorption data were analyzed and fitted well by Freundlich isotherm. Cr(VI) adsorption capacity of maghemite nanoparticles was compared favorably with other adsorbents like activated carbon and clay. Competition from common coexisting ions such as Na+, Ca2+, Mg2+, Cu2+, Ni2+, NO3-, and Cl-was ignorable, which illustrated the selective adsorption of Cr(VI) from wastewater. Regeneration studies verified that the maghemite nanoparticles, which underwent six successive adsorption-desorption processes, still retained the original metal removal capacity. In addition, the adsorption mechanisms were investigated using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopic techniques.
Original languageEnglish
Pages (from-to)4528-4536
Number of pages9
JournalWater Research
Volume39
Issue number18
DOIs
Publication statusPublished - 1 Nov 2005
Externally publishedYes

Keywords

  • Adsorption
  • Chromium
  • Common ion effect
  • Desorption
  • Freundlich isotherm

ASJC Scopus subject areas

  • Ecological Modelling
  • Water Science and Technology
  • Waste Management and Disposal
  • Pollution

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