Remarkably effective phosphanes simply with a PPh2moiety: Application to Pd-Catalysed cross-coupling reactions for tetra-ortho-substituted biaryl syntheses

Chau Ming So; Wing Kin Chow; Pui Ying Choy; Chak Po Lau; Fuk Yee Kwong

doi:10.1002/chem.201000723

Remarkably effective phosphanes simply with a PPh₂moiety: Application to Pd-Catalysed cross-coupling reactions for tetra-ortho-substituted biaryl syntheses

Chau Ming So, Wing Kin Chow, Pui Ying Choy, Chak Po Lau, Fuk Yee Kwong

Research output: Journal article publication › Journal article › Academic research › peer-review

79 Citations (Scopus)

Abstract

Chemical equation presented Expanding the horizons of ArPPh2: New applications of triarylphosphane ligands are presented. The Pd-L1 and Pd-L2 complexes offer exceptionally high activity in Suzuki-Miyaura cross-couplings of aryl chlorides. The extremely congested synthesis of tetraortho-substituted biaryl compounds is achieved for the first time by simply using triarylphosphane ligands. KGaA, Weinheim.

Original language	English
Pages (from-to)	7996-8001
Number of pages	6
Journal	Chemistry - A European Journal
Volume	16
Issue number	27
DOIs	https://doi.org/10.1002/chem.201000723
Publication status	Published - 19 Jul 2010

Keywords

Biaryls
Cross-coupling
Palladium
Phosphane ligands
Suzuki-Miyaura coupling

ASJC Scopus subject areas

General Chemistry

More information

10.1002/chem.201000723

Cite this

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title = "Remarkably effective phosphanes simply with a PPh2moiety: Application to Pd-Catalysed cross-coupling reactions for tetra-ortho-substituted biaryl syntheses",

abstract = "Chemical equation presented Expanding the horizons of ArPPh2: New applications of triarylphosphane ligands are presented. The Pd-L1 and Pd-L2 complexes offer exceptionally high activity in Suzuki-Miyaura cross-couplings of aryl chlorides. The extremely congested synthesis of tetraortho-substituted biaryl compounds is achieved for the first time by simply using triarylphosphane ligands. KGaA, Weinheim.",

keywords = "Biaryls, Cross-coupling, Palladium, Phosphane ligands, Suzuki-Miyaura coupling",

author = "So, {Chau Ming} and Chow, {Wing Kin} and Choy, {Pui Ying} and Lau, {Chak Po} and Kwong, {Fuk Yee}",

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Remarkably effective phosphanes simply with a PPh₂moiety: Application to Pd-Catalysed cross-coupling reactions for tetra-ortho-substituted biaryl syntheses. / So, Chau Ming; Chow, Wing Kin; Choy, Pui Ying et al.
In: Chemistry - A European Journal, Vol. 16, No. 27, 19.07.2010, p. 7996-8001.

Research output: Journal article publication › Journal article › Academic research › peer-review

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AU - Lau, Chak Po

AU - Kwong, Fuk Yee

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KW - Cross-coupling

KW - Palladium

KW - Phosphane ligands

KW - Suzuki-Miyaura coupling

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