Recognition of the intramolecular interaction: The syntheses and structures of ferrocene-conjugated polypyridine ligands and their complexes

Yegao Yin; Weidong Li; Liangchao Li; Kungkai Cheung; Wing Tak Wong

Recognition of the intramolecular interaction: The syntheses and structures of ferrocene-conjugated polypyridine ligands and their complexes

Yegao Yin, Weidong Li, Liangchao Li, Kungkai Cheung, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

Abstract

The syntheses and crystal structures of two ferrocene-conjugated polypyridine ligands (6-ferrocenyl-2, 2′-bipyridyl (fcbpy) and 4′ -ferrocenyl-2, 2′, 6′, 2″-terpyridine (fctpy) )and Mn(II) complex of fctpy(1) were described in this work. The electrochemical investigations of two ligands reveal that substitution of the polypyridyl group onto ferrocene causes a positive shift in the redox potential of ferrocene unit and the comparison of the structures of the complex 1 and free ligand fctpy shows that introduction of Mn(II) ion into the ligand does not significantly influence the structure of the ligand.

Original language	English
Journal	Wuhan Daxue Xuebao/Journal of Wuhan University
Volume	44
Issue number	4
Publication status	Published - 1 Dec 1998
Externally published	Yes

Keywords

Electrochemistry
Ferrocene
Mn(II) complex
Polypyridine

ASJC Scopus subject areas

Management of Technology and Innovation

Cite this

@article{796e7c98586a43e69065865bca1806a7,

title = "Recognition of the intramolecular interaction: The syntheses and structures of ferrocene-conjugated polypyridine ligands and their complexes",

abstract = "The syntheses and crystal structures of two ferrocene-conjugated polypyridine ligands (6-ferrocenyl-2, 2′-bipyridyl (fcbpy) and 4′ -ferrocenyl-2, 2′, 6′, 2″-terpyridine (fctpy) )and Mn(II) complex of fctpy(1) were described in this work. The electrochemical investigations of two ligands reveal that substitution of the polypyridyl group onto ferrocene causes a positive shift in the redox potential of ferrocene unit and the comparison of the structures of the complex 1 and free ligand fctpy shows that introduction of Mn(II) ion into the ligand does not significantly influence the structure of the ligand.",

keywords = "Electrochemistry, Ferrocene, Mn(II) complex, Polypyridine",

author = "Yegao Yin and Weidong Li and Liangchao Li and Kungkai Cheung and Wong, {Wing Tak}",

year = "1998",

month = dec,

day = "1",

language = "English",

volume = "44",

journal = "Wuhan Daxue Xuebao/Journal of Wuhan University",

issn = "0253-9888",

number = "4",

}

Recognition of the intramolecular interaction: The syntheses and structures of ferrocene-conjugated polypyridine ligands and their complexes. / Yin, Yegao; Li, Weidong; Li, Liangchao et al.
In: Wuhan Daxue Xuebao/Journal of Wuhan University, Vol. 44, No. 4, 01.12.1998.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Recognition of the intramolecular interaction: The syntheses and structures of ferrocene-conjugated polypyridine ligands and their complexes

AU - Yin, Yegao

AU - Li, Weidong

AU - Li, Liangchao

AU - Cheung, Kungkai

AU - Wong, Wing Tak

PY - 1998/12/1

Y1 - 1998/12/1

N2 - The syntheses and crystal structures of two ferrocene-conjugated polypyridine ligands (6-ferrocenyl-2, 2′-bipyridyl (fcbpy) and 4′ -ferrocenyl-2, 2′, 6′, 2″-terpyridine (fctpy) )and Mn(II) complex of fctpy(1) were described in this work. The electrochemical investigations of two ligands reveal that substitution of the polypyridyl group onto ferrocene causes a positive shift in the redox potential of ferrocene unit and the comparison of the structures of the complex 1 and free ligand fctpy shows that introduction of Mn(II) ion into the ligand does not significantly influence the structure of the ligand.

AB - The syntheses and crystal structures of two ferrocene-conjugated polypyridine ligands (6-ferrocenyl-2, 2′-bipyridyl (fcbpy) and 4′ -ferrocenyl-2, 2′, 6′, 2″-terpyridine (fctpy) )and Mn(II) complex of fctpy(1) were described in this work. The electrochemical investigations of two ligands reveal that substitution of the polypyridyl group onto ferrocene causes a positive shift in the redox potential of ferrocene unit and the comparison of the structures of the complex 1 and free ligand fctpy shows that introduction of Mn(II) ion into the ligand does not significantly influence the structure of the ligand.

KW - Electrochemistry

KW - Ferrocene

KW - Mn(II) complex

KW - Polypyridine

UR - http://www.scopus.com/inward/record.url?scp=11544358699&partnerID=8YFLogxK

M3 - Journal article

SN - 0253-9888

VL - 44

JO - Wuhan Daxue Xuebao/Journal of Wuhan University

JF - Wuhan Daxue Xuebao/Journal of Wuhan University

IS - 4

ER -

Recognition of the intramolecular interaction: The syntheses and structures of ferrocene-conjugated polypyridine ligands and their complexes

Abstract

Keywords

ASJC Scopus subject areas

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