Recent Advances in the Development of Chiral Gold Complexes for Catalytic Asymmetric Catalysis

Jia Jun Jiang; Man Kin Wong

doi:10.1002/asia.202001375

Recent Advances in the Development of Chiral Gold Complexes for Catalytic Asymmetric Catalysis

Jia Jun Jiang, Man Kin Wong (Corresponding Author)

Research output: Journal article publication › Review article › Academic research › peer-review

42 Citations (Scopus)

Abstract

Asymmetric gold catalysis has been rapidly developed in the past ten years. Breakthroughs have been made by rational design and meticulous selection of chiral ligands. This review summarizes newly developed gold-catalyzed enantioselective organic transformations and recent progress in ligand design (since 2016), organized according to different types of chiral ligands, including bisphosphine ligands, monophosphine ligands, phosphite-derived ligands, and N-heterocyclic carbene ligands for asymmetric gold(I) catalysis as well as heterocyclic carbene ligands and oxazoline ligands for asymmetric gold(III) catalysis.

Original language	English
Pages (from-to)	364-377
Number of pages	14
Journal	Chemistry - An Asian Journal
Volume	16
Issue number	5
DOIs	https://doi.org/10.1002/asia.202001375
Publication status	Published - 1 Mar 2021

Keywords

asymmetric catalysis
enantioselectivity
gold
homogeneous catalysis
ligand design

ASJC Scopus subject areas

Biochemistry
Organic Chemistry

More information

10.1002/asia.202001375

http://hdl.handle.net/10397/100093

Cite this

@article{c9b2b1b6aedf448892ef00029292167c,

title = "Recent Advances in the Development of Chiral Gold Complexes for Catalytic Asymmetric Catalysis",

abstract = "Asymmetric gold catalysis has been rapidly developed in the past ten years. Breakthroughs have been made by rational design and meticulous selection of chiral ligands. This review summarizes newly developed gold-catalyzed enantioselective organic transformations and recent progress in ligand design (since 2016), organized according to different types of chiral ligands, including bisphosphine ligands, monophosphine ligands, phosphite-derived ligands, and N-heterocyclic carbene ligands for asymmetric gold(I) catalysis as well as heterocyclic carbene ligands and oxazoline ligands for asymmetric gold(III) catalysis.",

keywords = "asymmetric catalysis, enantioselectivity, gold, homogeneous catalysis, ligand design",

author = "Jiang, {Jia Jun} and Wong, {Man Kin}",

note = "Funding Information: The authors are grateful for the financial support of the Hong Kong Research Grants Council (PolyU 153000/19P), the State Key Laboratory of Chemical Biology and Drug Discovery, and The Hong Kong Polytechnic University (G‐UACN) Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH",

year = "2021",

month = mar,

day = "1",

doi = "10.1002/asia.202001375",

language = "English",

volume = "16",

pages = "364--377",

journal = "Chemistry - An Asian Journal",

issn = "1861-4728",

publisher = "John Wiley and Sons Ltd",

number = "5",

}

TY - JOUR

T1 - Recent Advances in the Development of Chiral Gold Complexes for Catalytic Asymmetric Catalysis

AU - Jiang, Jia Jun

AU - Wong, Man Kin

N1 - Funding Information: The authors are grateful for the financial support of the Hong Kong Research Grants Council (PolyU 153000/19P), the State Key Laboratory of Chemical Biology and Drug Discovery, and The Hong Kong Polytechnic University (G‐UACN) Publisher Copyright: © 2021 Wiley-VCH GmbH

PY - 2021/3/1

Y1 - 2021/3/1

N2 - Asymmetric gold catalysis has been rapidly developed in the past ten years. Breakthroughs have been made by rational design and meticulous selection of chiral ligands. This review summarizes newly developed gold-catalyzed enantioselective organic transformations and recent progress in ligand design (since 2016), organized according to different types of chiral ligands, including bisphosphine ligands, monophosphine ligands, phosphite-derived ligands, and N-heterocyclic carbene ligands for asymmetric gold(I) catalysis as well as heterocyclic carbene ligands and oxazoline ligands for asymmetric gold(III) catalysis.

AB - Asymmetric gold catalysis has been rapidly developed in the past ten years. Breakthroughs have been made by rational design and meticulous selection of chiral ligands. This review summarizes newly developed gold-catalyzed enantioselective organic transformations and recent progress in ligand design (since 2016), organized according to different types of chiral ligands, including bisphosphine ligands, monophosphine ligands, phosphite-derived ligands, and N-heterocyclic carbene ligands for asymmetric gold(I) catalysis as well as heterocyclic carbene ligands and oxazoline ligands for asymmetric gold(III) catalysis.

KW - asymmetric catalysis

KW - enantioselectivity

KW - gold

KW - homogeneous catalysis

KW - ligand design

UR - http://www.scopus.com/inward/record.url?scp=85099979215&partnerID=8YFLogxK

U2 - 10.1002/asia.202001375

DO - 10.1002/asia.202001375

M3 - Review article

C2 - 33386691

AN - SCOPUS:85099979215

SN - 1861-4728

VL - 16

SP - 364

EP - 377

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 5

ER -

Recent Advances in the Development of Chiral Gold Complexes for Catalytic Asymmetric Catalysis

Abstract

Keywords

ASJC Scopus subject areas

More information

Other files and links

Fingerprint

Cite this