Recent Advances in Superhydrophobic and Antibacterial Cellulose-Based Fibers and Fabrics: Bio-inspiration, Strategies, and Applications

Cellulose-based fabrics are ubiquitous in our daily lives. They are the preferred choice for bedding materials, active sportswear, and next-to-skin apparels. However, the hydrophilic and polysaccharide characteristics of cellulose materials make them vulnerable to bacterial attack and pathogen infection. The design of antibacterial cellulose fabrics has been a long-term and on-going effort. Fabrication strategies based on the construction of surface micro-/nanostructure, chemical modification, and the application of antibacterial agents have been extensively investigated by many research groups worldwide. This review systematically discusses recent research on super-hydrophobic and antibacterial cellulose fabrics, focusing on morphology construction and surface modification. First, natural surfaces showing liquid-repellent and antibacterial properties are introduced and the mechanisms behind are explained. Then, the strategies for fabricating super-hydrophobic cellulose fabrics are summarized, and the contribution of the liquid-repellent function to reducing the adhesion of live bacteria and removing dead bacteria is elucidated. Representative studies on cellulose fabrics functionalized with super-hydrophobic and antibacterial properties are discussed in detail, and their potential applications are also introduced. Finally, the challenges in achieving super-hydrophobic antibacterial cellulose fabrics are discussed, and the future research direction in this area is proposed. Graphical Abstract: The figure summarizes the natural surfaces and the main fabrication strategies of superhydrophobic antibacterial cellulose fabrics and their potential applications. [Figure not available: see fulltext.]