Reactivity of chiral diiminodiphosphine ligands towards pdCl2(PhCN)2: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes

Wai Kwok Wong, Li Lu Zhang, Yang Chen, Wai Yeung Wong, Wing Tak Wong, Feng Xuc, Thomas C.W. Mak

Research output: Journal article publicationJournal articleAcademic researchpeer-review

11 Citations (Scopus)

Abstract

The interaction of PdCl2(PhCN)2with (S)-N,N′;-bis[2-(diphenylphosphino)benzylidene]-2,2′-diimino-l, 1′-binaphthylene (S)-L′ and (S,S′)-N,N′-bis[2-(diphenylphosphino)benzy lidene]-1,2-diimino-1,2-diphenylethane (S,S′)-L2 gave the dimeric complex {PdCl[2-(Ph2P)C6H4CH=N]}21 and the dinuclear complex {ci5-PdCl2[2-(Ph2P)C6H4CH= NCH(Ph)CH(C6H4PPh2-2)=NC6H4(PPh2)-2]PdCl} {Cl} 2, respectively, whose structures were ascertained by X-ray crystallography.
Original languageEnglish
Pages (from-to)1397-1398
Number of pages2
JournalJournal of the Chemical Society, Dalton Transactions
Issue number9
DOIs
Publication statusPublished - 1 Dec 2000
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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