Reactivity of chiral diiminodiphosphine ligands towards pdCl2(PhCN)2: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes

Wai Kwok Wong; Li Lu Zhang; Yang Chen; Wai Yeung Wong; Wing Tak Wong; Feng Xuc; Thomas C.W. Mak

doi:10.1039/b001245i

Reactivity of chiral diiminodiphosphine ligands towards pdCl₂(PhCN)₂: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes

Wai Kwok Wong, Li Lu Zhang, Yang Chen, Wai Yeung Wong, Wing Tak Wong, Feng Xuc, Thomas C.W. Mak

Research output: Journal article publication › Journal article › Academic research › peer-review

11 Citations (Scopus)

Abstract

The interaction of PdCl2(PhCN)2with (S)-N,N′;-bis[2-(diphenylphosphino)benzylidene]-2,2′-diimino-l, 1′-binaphthylene (S)-L′ and (S,S′)-N,N′-bis[2-(diphenylphosphino)benzy lidene]-1,2-diimino-1,2-diphenylethane (S,S′)-L2 gave the dimeric complex {PdCl[2-(Ph2P)C6H4CH=N]}21 and the dinuclear complex {ci5-PdCl2[2-(Ph2P)C6H4CH= NCH(Ph)CH(C6H4PPh2-2)=NC6H4(PPh2)-2]PdCl} {Cl} 2, respectively, whose structures were ascertained by X-ray crystallography.

Original language	English
Pages (from-to)	1397-1398
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	9
DOIs	https://doi.org/10.1039/b001245i
Publication status	Published - 1 Dec 2000
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1039/b001245i

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title = "Reactivity of chiral diiminodiphosphine ligands towards pdCl2(PhCN)2: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes",

abstract = "The interaction of PdCl2(PhCN)2with (S)-N,N′;-bis[2-(diphenylphosphino)benzylidene]-2,2′-diimino-l, 1′-binaphthylene (S)-L′ and (S,S′)-N,N′-bis[2-(diphenylphosphino)benzy lidene]-1,2-diimino-1,2-diphenylethane (S,S′)-L2 gave the dimeric complex {PdCl[2-(Ph2P)C6H4CH=N]}21 and the dinuclear complex {ci5-PdCl2[2-(Ph2P)C6H4CH= NCH(Ph)CH(C6H4PPh2-2)=NC6H4(PPh2)-2]PdCl} {Cl} 2, respectively, whose structures were ascertained by X-ray crystallography.",

author = "Wong, {Wai Kwok} and Zhang, {Li Lu} and Yang Chen and Wong, {Wai Yeung} and Wong, {Wing Tak} and Feng Xuc and Mak, {Thomas C.W.}",

year = "2000",

month = dec,

day = "1",

doi = "10.1039/b001245i",

language = "English",

pages = "1397--1398",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "9",

}

Reactivity of chiral diiminodiphosphine ligands towards pdCl₂(PhCN)₂: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes. / Wong, Wai Kwok; Zhang, Li Lu; Chen, Yang et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 9, 01.12.2000, p. 1397-1398.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Reactivity of chiral diiminodiphosphine ligands towards pdCl2(PhCN)2: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes

AU - Wong, Wai Kwok

AU - Zhang, Li Lu

AU - Chen, Yang

AU - Wong, Wai Yeung

AU - Wong, Wing Tak

AU - Xuc, Feng

AU - Mak, Thomas C.W.

PY - 2000/12/1

Y1 - 2000/12/1

N2 - The interaction of PdCl2(PhCN)2with (S)-N,N′;-bis[2-(diphenylphosphino)benzylidene]-2,2′-diimino-l, 1′-binaphthylene (S)-L′ and (S,S′)-N,N′-bis[2-(diphenylphosphino)benzy lidene]-1,2-diimino-1,2-diphenylethane (S,S′)-L2 gave the dimeric complex {PdCl[2-(Ph2P)C6H4CH=N]}21 and the dinuclear complex {ci5-PdCl2[2-(Ph2P)C6H4CH= NCH(Ph)CH(C6H4PPh2-2)=NC6H4(PPh2)-2]PdCl} {Cl} 2, respectively, whose structures were ascertained by X-ray crystallography.

AB - The interaction of PdCl2(PhCN)2with (S)-N,N′;-bis[2-(diphenylphosphino)benzylidene]-2,2′-diimino-l, 1′-binaphthylene (S)-L′ and (S,S′)-N,N′-bis[2-(diphenylphosphino)benzy lidene]-1,2-diimino-1,2-diphenylethane (S,S′)-L2 gave the dimeric complex {PdCl[2-(Ph2P)C6H4CH=N]}21 and the dinuclear complex {ci5-PdCl2[2-(Ph2P)C6H4CH= NCH(Ph)CH(C6H4PPh2-2)=NC6H4(PPh2)-2]PdCl} {Cl} 2, respectively, whose structures were ascertained by X-ray crystallography.

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U2 - 10.1039/b001245i

DO - 10.1039/b001245i

M3 - Journal article

SN - 1470-479X

SP - 1397

EP - 1398

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 9

ER -

Reactivity of chiral diiminodiphosphine ligands towards pdCl₂(PhCN)₂: Synthesis and crystal structures of two unexpected dinuclear palladium(n) complexes

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