Reaction of [N(PPh3)2][Os3(μ-H)(CO)11] with [Cu(PPh3)2BH4]. Crystal and molecular structures of [Os3(μ-H)(μ-OH)(CO)10] and two [Os3(μ-H)(μ-OH)(CO)8(PPh3)2] isomeric clusters

Winnie Ging Yee Ho; Wing Tak Wong

doi:10.1016/0277-5387(95)00208-A

Reaction of [N(PPh₃)₂][Os₃(μ-H)(CO)₁₁] with [Cu(PPh₃)₂BH₄]. Crystal and molecular structures of [Os₃(μ-H)(μ-OH)(CO)₁₀] and two [Os₃(μ-H)(μ-OH)(CO)₈(PPh₃)₂] isomeric clusters

Winnie Ging Yee Ho
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

15 Citations (Scopus)

Abstract

Reaction of [N(PPh3)2][Os3(μ-H)(CO)11] with [Cu(PPh3)2BH4] in CH2Cl2at room temperature affords [Os3(μ-H)(μ-OH)(CO)10] (1) and two isomers 2a and 2b with a molecular formula [Os3(μ-H)(μ-OH)(CO)8(PPh3)2]. Clusters 1, 2a and 2b are all air- and moisture-stable and have been fully characterized by IR, NMR, MS and X-ray crystallography. The molecular structures of 2a and 2b are different in the substitution positions of the PPh3.

Original language	English
Pages (from-to)	2849-2855
Number of pages	7
Journal	Polyhedron
Volume	14
Issue number	20-21
DOIs	https://doi.org/10.1016/0277-5387(95)00208-A
Publication status	Published - 1 Jan 1995
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0277-5387(95)00208-A

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title = "Reaction of [N(PPh3)2][Os3(μ-H)(CO)11] with [Cu(PPh3)2BH4]. Crystal and molecular structures of [Os3(μ-H)(μ-OH)(CO)10] and two [Os3(μ-H)(μ-OH)(CO)8(PPh3)2] isomeric clusters",

abstract = "Reaction of [N(PPh3)2][Os3(μ-H)(CO)11] with [Cu(PPh3)2BH4] in CH2Cl2at room temperature affords [Os3(μ-H)(μ-OH)(CO)10] (1) and two isomers 2a and 2b with a molecular formula [Os3(μ-H)(μ-OH)(CO)8(PPh3)2]. Clusters 1, 2a and 2b are all air- and moisture-stable and have been fully characterized by IR, NMR, MS and X-ray crystallography. The molecular structures of 2a and 2b are different in the substitution positions of the PPh3.",

author = "Ho, \{Winnie Ging Yee\} and Wong, \{Wing Tak\}",

year = "1995",

month = jan,

day = "1",

doi = "10.1016/0277-5387(95)00208-A",

language = "English",

volume = "14",

pages = "2849--2855",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

number = "20-21",

}

Reaction of [N(PPh₃)₂][Os₃(μ-H)(CO)₁₁] with [Cu(PPh₃)₂BH₄]. Crystal and molecular structures of [Os₃(μ-H)(μ-OH)(CO)₁₀] and two [Os₃(μ-H)(μ-OH)(CO)₈(PPh₃)₂] isomeric clusters. / Ho, Winnie Ging Yee; Wong, Wing Tak.
In: Polyhedron, Vol. 14, No. 20-21, 01.01.1995, p. 2849-2855.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Reaction of [N(PPh3)2][Os3(μ-H)(CO)11] with [Cu(PPh3)2BH4]. Crystal and molecular structures of [Os3(μ-H)(μ-OH)(CO)10] and two [Os3(μ-H)(μ-OH)(CO)8(PPh3)2] isomeric clusters

AU - Ho, Winnie Ging Yee

AU - Wong, Wing Tak

PY - 1995/1/1

Y1 - 1995/1/1

N2 - Reaction of [N(PPh3)2][Os3(μ-H)(CO)11] with [Cu(PPh3)2BH4] in CH2Cl2at room temperature affords [Os3(μ-H)(μ-OH)(CO)10] (1) and two isomers 2a and 2b with a molecular formula [Os3(μ-H)(μ-OH)(CO)8(PPh3)2]. Clusters 1, 2a and 2b are all air- and moisture-stable and have been fully characterized by IR, NMR, MS and X-ray crystallography. The molecular structures of 2a and 2b are different in the substitution positions of the PPh3.

AB - Reaction of [N(PPh3)2][Os3(μ-H)(CO)11] with [Cu(PPh3)2BH4] in CH2Cl2at room temperature affords [Os3(μ-H)(μ-OH)(CO)10] (1) and two isomers 2a and 2b with a molecular formula [Os3(μ-H)(μ-OH)(CO)8(PPh3)2]. Clusters 1, 2a and 2b are all air- and moisture-stable and have been fully characterized by IR, NMR, MS and X-ray crystallography. The molecular structures of 2a and 2b are different in the substitution positions of the PPh3.

UR - https://www.scopus.com/pages/publications/0345855814

U2 - 10.1016/0277-5387(95)00208-A

DO - 10.1016/0277-5387(95)00208-A

M3 - Journal article

SN - 0277-5387

VL - 14

SP - 2849

EP - 2855

JO - Polyhedron

JF - Polyhedron

IS - 20-21

ER -

Reaction of [N(PPh₃)₂][Os₃(μ-H)(CO)₁₁] with [Cu(PPh₃)₂BH₄]. Crystal and molecular structures of [Os₃(μ-H)(μ-OH)(CO)₁₀] and two [Os₃(μ-H)(μ-OH)(CO)₈(PPh₃)₂] isomeric clusters

Abstract

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