Reaction of [(μ-H)Os3(CO)11]-anion with dioxygen

Christopher J. Cathey; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Wing Tak Wong

doi:10.1016/0022-328X(93)80171-7

Reaction of [(μ-H)Os₃(CO)₁₁]^-anion with dioxygen

Christopher J. Cathey, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

10 Citations (Scopus)

Abstract

The anion [(μ-H)Os3(CO)11]-reacts with dioxygen in solution to give a yellow species which further reacts with Os6(CO)18to yield [(μ-H)Os3(CO)10.(/gm2-O2C).Os6(CO)17]-. The structure of the oxygen intermediate is proposed, and a mechanism of the reaction suggested.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	450
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(93)80171-7
Publication status	Published - 18 May 1993
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(93)80171-7

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title = "Reaction of [(μ-H)Os3(CO)11]-anion with dioxygen",

abstract = "The anion [(μ-H)Os3(CO)11]-reacts with dioxygen in solution to give a yellow species which further reacts with Os6(CO)18to yield [(μ-H)Os3(CO)10.(/gm2-O2C).Os6(CO)17]-. The structure of the oxygen intermediate is proposed, and a mechanism of the reaction suggested.",

author = "Cathey, {Christopher J.} and Johnson, {Brian F.G.} and Jack Lewis and Raithby, {Paul R.} and Wong, {Wing Tak}",

year = "1993",

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TY - JOUR

T1 - Reaction of [(μ-H)Os3(CO)11]-anion with dioxygen

AU - Cathey, Christopher J.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Wong, Wing Tak

PY - 1993/5/18

Y1 - 1993/5/18

N2 - The anion [(μ-H)Os3(CO)11]-reacts with dioxygen in solution to give a yellow species which further reacts with Os6(CO)18to yield [(μ-H)Os3(CO)10.(/gm2-O2C).Os6(CO)17]-. The structure of the oxygen intermediate is proposed, and a mechanism of the reaction suggested.

AB - The anion [(μ-H)Os3(CO)11]-reacts with dioxygen in solution to give a yellow species which further reacts with Os6(CO)18to yield [(μ-H)Os3(CO)10.(/gm2-O2C).Os6(CO)17]-. The structure of the oxygen intermediate is proposed, and a mechanism of the reaction suggested.

UR - http://www.scopus.com/inward/record.url?scp=0039544106&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(93)80171-7

DO - 10.1016/0022-328X(93)80171-7

M3 - Journal article

SN - 0022-328X

VL - 450

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Reaction of [(μ-H)Os₃(CO)₁₁]^-anion with dioxygen

Abstract

ASJC Scopus subject areas

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