Quinoxaline-based conjugated polymers containing ruthenium(II) bipyridine metal complex

Po King Ng; Xiong Gong; Wing Tak Wong; Wai Kin Chan

doi:10.1002/marc.1997.030181203

Quinoxaline-based conjugated polymers containing ruthenium(II) bipyridine metal complex

Po King Ng, Xiong Gong, Wing Tak Wong, Wai Kin Chan

Research output: Journal article publication › Journal article › Academic research › peer-review

35 Citations (Scopus)

Abstract

A series of novel quinoxaline-based conjugated polymers which contain a ruthenium(II) bipyridine complex were synthesized by the Suzuki coupling reaction. UV/VIS spectroscopy showed that the spectral features of the polymers are dependent on the amount of metal complex present. Results from excitation and emission spectroscopy suggest an energy transfer between the backbone and the metal complex. The polymers exhibit hole carrier mobilities of ≈ 10-5cm2· V-1· s-1, which is comparable to organic photoconductors.

Original language	English
Pages (from-to)	1009-1016
Number of pages	8
Journal	Macromolecular Rapid Communications
Volume	18
Issue number	12
DOIs	https://doi.org/10.1002/marc.1997.030181203
Publication status	Published - 1 Jan 1997
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/marc.1997.030181203

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AB - A series of novel quinoxaline-based conjugated polymers which contain a ruthenium(II) bipyridine complex were synthesized by the Suzuki coupling reaction. UV/VIS spectroscopy showed that the spectral features of the polymers are dependent on the amount of metal complex present. Results from excitation and emission spectroscopy suggest an energy transfer between the backbone and the metal complex. The polymers exhibit hole carrier mobilities of ≈ 10-5cm2· V-1· s-1, which is comparable to organic photoconductors.

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DO - 10.1002/marc.1997.030181203

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Quinoxaline-based conjugated polymers containing ruthenium(II) bipyridine metal complex

Abstract

ASJC Scopus subject areas

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