Proton-bridged dinuclear (salen)Ru carbene complexes: Synthesis, structure, and reactivity of {[(salchda)Ru=C(OR)(CH=CPh2)]2 ·H}+

Chun Yuen Wong; Wai Lun Man; Chao Wang; Hoi Lun Kwong; Wai Yeung Wong; Tai Chu Lau

doi:10.1021/om701166y

Proton-bridged dinuclear (salen)Ru carbene complexes: Synthesis, structure, and reactivity of {[(salchda)Ru=C(OR)(CH=CPh2)]2 ·H}+

Chun Yuen Wong, Wai Lun Man, Chao Wang, Hoi Lun Kwong, Wai Yeung Wong, Tai Chu Lau

Research output: Journal article publication › Journal article › Academic research › peer-review

22 Citations (Scopus)

Abstract

Hydrogen-bridged dinuclear ruthenium carbene complexes supported by salen have been prepared and found to be active catalysts for the cyclopropanation of alkenes; electrochemical and theoretical studies suggest the existence of electronic communication between the Ru centers.

Original language	English
Pages (from-to)	324-326
Number of pages	3
Journal	Organometallics
Volume	27
Issue number	3
DOIs	https://doi.org/10.1021/om701166y
Publication status	Published - 11 Feb 2008
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry
Organic Chemistry

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10.1021/om701166y

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title = "Proton-bridged dinuclear (salen)Ru carbene complexes: Synthesis, structure, and reactivity of {[(salchda)Ru=C(OR)(CH=CPh2)]2 ·H}+",

abstract = "Hydrogen-bridged dinuclear ruthenium carbene complexes supported by salen have been prepared and found to be active catalysts for the cyclopropanation of alkenes; electrochemical and theoretical studies suggest the existence of electronic communication between the Ru centers.",

author = "Wong, {Chun Yuen} and Man, {Wai Lun} and Chao Wang and Kwong, {Hoi Lun} and Wong, {Wai Yeung} and Lau, {Tai Chu}",

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AU - Man, Wai Lun

AU - Wang, Chao

AU - Kwong, Hoi Lun

AU - Wong, Wai Yeung

AU - Lau, Tai Chu

PY - 2008/2/11

Y1 - 2008/2/11

N2 - Hydrogen-bridged dinuclear ruthenium carbene complexes supported by salen have been prepared and found to be active catalysts for the cyclopropanation of alkenes; electrochemical and theoretical studies suggest the existence of electronic communication between the Ru centers.

AB - Hydrogen-bridged dinuclear ruthenium carbene complexes supported by salen have been prepared and found to be active catalysts for the cyclopropanation of alkenes; electrochemical and theoretical studies suggest the existence of electronic communication between the Ru centers.

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U2 - 10.1021/om701166y

DO - 10.1021/om701166y

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ER -

Proton-bridged dinuclear (salen)Ru carbene complexes: Synthesis, structure, and reactivity of {[(salchda)Ru=C(OR)(CH=CPh2)]2 ·H}+

Abstract

ASJC Scopus subject areas

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