Preparation of organosilicate/PVDF composites with enhanced piezoelectricity and pyroelectricity by stretching

Fu An He; Kai Lin; Dong Liang Shi; Hui Jun Wu; Hua Kun Huang; Jun Jun Chen; Fang Chen; Kwok Ho Lam

doi:10.1016/j.compscitech.2016.10.031

Preparation of organosilicate/PVDF composites with enhanced piezoelectricity and pyroelectricity by stretching

Fu An He, Kai Lin, Dong Liang Shi, Hui Jun Wu, Hua Kun Huang, Jun Jun Chen, Fang Chen, Kwok Ho Lam

Research output: Journal article publication › Journal article › Academic research › peer-review

68 Citations (Scopus)

Abstract

It was confirmed by scanning electron microscopy that OS was homogeneously distributed in the PVDF matrix. The results of differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), and wide angle X-ray diffraction indicated that the incorporation of OS along with stretching treatment could effectively transform PVDF crystallization from the stable α phase to the most useful electroactive β phase. The interfacial interaction between PVDF and OS was analyzed by X-ray photoelectron spectroscopy and zeta potential. The dielectric properties, AC conductivities, mechanical properties, Rockwell hardness, and thermal conductivity of resultant OS/PVDF composites have been measured. More importantly, the piezoelectric coefficient d33and pyroelectric coefficient p of stretched OS/PVDF composites were enhanced significantly in comparison with the pure PVDF, making them promising materials for self-powered electronic systems, thermal detectors, sensors, and actuators.

Original language	English
Pages (from-to)	138-147
Number of pages	10
Journal	Composites Science and Technology
Volume	137
DOIs	https://doi.org/10.1016/j.compscitech.2016.10.031
Publication status	Published - 12 Dec 2016

Keywords

Composites
Organosilicate
Piezoelectricity
Poly(vinylidene fluoride)
Pyroelectricity

ASJC Scopus subject areas

Ceramics and Composites
Engineering(all)

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10.1016/j.compscitech.2016.10.031

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@article{644c0460796d44ea903f574bada1504d,

title = "Preparation of organosilicate/PVDF composites with enhanced piezoelectricity and pyroelectricity by stretching",

abstract = "It was confirmed by scanning electron microscopy that OS was homogeneously distributed in the PVDF matrix. The results of differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), and wide angle X-ray diffraction indicated that the incorporation of OS along with stretching treatment could effectively transform PVDF crystallization from the stable α phase to the most useful electroactive β phase. The interfacial interaction between PVDF and OS was analyzed by X-ray photoelectron spectroscopy and zeta potential. The dielectric properties, AC conductivities, mechanical properties, Rockwell hardness, and thermal conductivity of resultant OS/PVDF composites have been measured. More importantly, the piezoelectric coefficient d33and pyroelectric coefficient p of stretched OS/PVDF composites were enhanced significantly in comparison with the pure PVDF, making them promising materials for self-powered electronic systems, thermal detectors, sensors, and actuators.",

keywords = "Composites, Organosilicate, Piezoelectricity, Poly(vinylidene fluoride), Pyroelectricity",

author = "He, {Fu An} and Kai Lin and Shi, {Dong Liang} and Wu, {Hui Jun} and Huang, {Hua Kun} and Chen, {Jun Jun} and Fang Chen and Lam, {Kwok Ho}",

year = "2016",

month = dec,

day = "12",

doi = "10.1016/j.compscitech.2016.10.031",

language = "English",

volume = "137",

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journal = "Composites Science and Technology",

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TY - JOUR

T1 - Preparation of organosilicate/PVDF composites with enhanced piezoelectricity and pyroelectricity by stretching

AU - He, Fu An

AU - Lin, Kai

AU - Shi, Dong Liang

AU - Wu, Hui Jun

AU - Huang, Hua Kun

AU - Chen, Jun Jun

AU - Chen, Fang

AU - Lam, Kwok Ho

PY - 2016/12/12

Y1 - 2016/12/12

N2 - It was confirmed by scanning electron microscopy that OS was homogeneously distributed in the PVDF matrix. The results of differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), and wide angle X-ray diffraction indicated that the incorporation of OS along with stretching treatment could effectively transform PVDF crystallization from the stable α phase to the most useful electroactive β phase. The interfacial interaction between PVDF and OS was analyzed by X-ray photoelectron spectroscopy and zeta potential. The dielectric properties, AC conductivities, mechanical properties, Rockwell hardness, and thermal conductivity of resultant OS/PVDF composites have been measured. More importantly, the piezoelectric coefficient d33and pyroelectric coefficient p of stretched OS/PVDF composites were enhanced significantly in comparison with the pure PVDF, making them promising materials for self-powered electronic systems, thermal detectors, sensors, and actuators.

AB - It was confirmed by scanning electron microscopy that OS was homogeneously distributed in the PVDF matrix. The results of differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), and wide angle X-ray diffraction indicated that the incorporation of OS along with stretching treatment could effectively transform PVDF crystallization from the stable α phase to the most useful electroactive β phase. The interfacial interaction between PVDF and OS was analyzed by X-ray photoelectron spectroscopy and zeta potential. The dielectric properties, AC conductivities, mechanical properties, Rockwell hardness, and thermal conductivity of resultant OS/PVDF composites have been measured. More importantly, the piezoelectric coefficient d33and pyroelectric coefficient p of stretched OS/PVDF composites were enhanced significantly in comparison with the pure PVDF, making them promising materials for self-powered electronic systems, thermal detectors, sensors, and actuators.

KW - Composites

KW - Organosilicate

KW - Piezoelectricity

KW - Poly(vinylidene fluoride)

KW - Pyroelectricity

UR - http://www.scopus.com/inward/record.url?scp=84994819115&partnerID=8YFLogxK

U2 - 10.1016/j.compscitech.2016.10.031

DO - 10.1016/j.compscitech.2016.10.031

M3 - Journal article

SN - 0266-3538

VL - 137

SP - 138

EP - 147

JO - Composites Science and Technology

JF - Composites Science and Technology

ER -

Preparation of organosilicate/PVDF composites with enhanced piezoelectricity and pyroelectricity by stretching

Abstract

Keywords

ASJC Scopus subject areas

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