Preparation and characterization of bio-safe activated charcoal derived from coffee waste residue and its application for removal of lead and copper ions

Po Ting Yeung, Po Yee Chung, Hing Cheung Tsang, Cheuk On Tang, Gregory Yin-Ming Cheng, Roberto Gambari, Chung Hin Chui, Kim Hung Lam

Research output: Journal article publicationJournal articleAcademic researchpeer-review

33 Citations (Scopus)

Abstract

Activated charcoal was prepared by the pyrolysis of coffee ground waste residues impregnated by phosphoric acid and potassium hydroxide at 600 °C. In our study, spent coffee was collected from the university canteen and the prepared activated charcoal impregnated with potassium hydroxide gave the highest surface area of 708.1 ± 0.1 m2 g-1, which was determined by using the methylene blue adsorption method. The activated charcoal was characterized by using scanning electron microscopy and Fourier transform infrared spectroscopy. In order to ensure that the activated charcoal produced is bio-safe, all samples were tested for possible toxic substances, including toxic heavy metals by using ICP-OES, and toxic organics such as acrylamide by using chromatography methods. In addition, all samples showed no ecotoxicity towards Escherichia coli and no cytotoxicity toward human HaCaT skin cells. The phosphoric acid activated charcoal demonstrated a high Q max of 95.2 and 38.2 mg g-1, respectively for lead and copper adsorption. For potassium hydroxide activated charcoal, the values of Qmax were found to be 45.4 and 21.2 mg g-1, respectively for lead and copper adsorption.
Original languageEnglish
Pages (from-to)38839-38847
Number of pages9
JournalRSC Advances
Volume4
Issue number73
DOIs
Publication statusPublished - 1 Jan 2014

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

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