Abstract
A general approach to the synthesis of optically pure 3,3'diaryl chiral sulfonimides (CSIs) from racemic BINOL has been developed. ortho-Lithiation is directed by the sulfonyl groups, and the resulting dihalides serve as the common precursors for the aryl-substituted CSIs. KGaA, Weinheim.
Original language | English |
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Pages (from-to) | 4181-4184 |
Number of pages | 4 |
Journal | European Journal of Organic Chemistry |
Issue number | 22 |
DOIs | |
Publication status | Published - 1 Aug 2010 |
Externally published | Yes |
Keywords
- Bransted acids
- Chirality
- Organocatalysis
- Sulfonimides
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry