Polyelectrolyte network-surfactant complexes with shape memory effect

Yiping Cao, Ying Guan, Wenchuan Zhang, Yuxing Peng, Pei Li, Albert S.C. Chan

Research output: Journal article publicationJournal articleAcademic researchpeer-review

Abstract

The complex of Poly(acrylic acid-co-acrylamide) network with cetyl-trimethylammonium bromide (P(AA-co-Am)-C16TAB) was synthesized. It has shape memory behavior due to the formation of thermodynamically homogeneous structure. A specific feature of this type of shape memory complex is that the transition temperature at which the complex abruptly becomes soft and deforms can be controlled by changing the degree of cross-linkage, which enables one to adjust the shape memory effect at desired temperature. Mechanism and process of the shape memory behavior were discussed.
Original languageEnglish
Pages (from-to)375-383
Number of pages9
JournalInternational Journal of Polymeric Materials and Polymeric Biomaterials
Volume53
Issue number4
DOIs
Publication statusPublished - 1 Apr 2004

Keywords

  • Cetyltrimethylammonium bromide
  • Complexes
  • Networks
  • Poly(acrylic acid-co-acrylamide)
  • Polyelectrolyte
  • Shape memory

ASJC Scopus subject areas

  • Analytical Chemistry
  • General Chemical Engineering
  • Polymers and Plastics

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