Picosecond time-resolved resonance Raman observation of the iso-CH2Cl-I and iso-CH2I-Cl photoproducts from the "photoisomerization" reactions of CH2ICl in the solution phase

Wai Ming Kwok; Chensheng Ma; Anthony W. Parker; David Phillips; Michael Towrie; Pavel Matousek; Xuming Zheng; David Lee Phillips

doi:10.1063/1.1362178

Picosecond time-resolved resonance Raman observation of the iso-CH₂Cl-I and iso-CH₂I-Cl photoproducts from the "photoisomerization" reactions of CH₂ICl in the solution phase

Wai Ming Kwok
, Chensheng Ma
, Anthony W. Parker
, David Phillips
, Michael Towrie
, Pavel Matousek
, Xuming Zheng
, David Lee Phillips

Research output: Journal article publication › Journal article › Academic research › peer-review

43 Citations (Scopus)

Abstract

A preliminary pecosecond Stokes time-resolved resonance Raman investigation was made of the initial formation and subsequent decay of the photoproduct produced following 267 nm excitaiton of CH2ClI in acetonitrile solution. A coparision was made between density-functional theroy computations for portable photoproduct species and the results from a femtosecond transient absorption study to Raman spectra. This comparision indicated that the iso-CH2ClI was aminly produced and associated with the 460 nm transient absorption band.

Original language	English
Pages (from-to)	7536-7543
Number of pages	8
Journal	Journal of Chemical Physics
Volume	114
Issue number	17
DOIs	https://doi.org/10.1063/1.1362178
Publication status	Published - 1 May 2001
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

More information

10.1063/1.1362178

Cite this

Kwok, W. M., Ma, C., Parker, A. W., Phillips, D., Towrie, M., Matousek, P., Zheng, X., & Phillips, D. L. (2001). Picosecond time-resolved resonance Raman observation of the iso-CH₂Cl-I and iso-CH₂I-Cl photoproducts from the "photoisomerization" reactions of CH₂ICl in the solution phase. Journal of Chemical Physics, 114(17), 7536-7543. https://doi.org/10.1063/1.1362178

@article{de787ccbefb045af837f83076a31fdc1,

title = "Picosecond time-resolved resonance Raman observation of the iso-CH2Cl-I and iso-CH2I-Cl photoproducts from the {"}photoisomerization{"} reactions of CH2ICl in the solution phase",

abstract = "A preliminary pecosecond Stokes time-resolved resonance Raman investigation was made of the initial formation and subsequent decay of the photoproduct produced following 267 nm excitaiton of CH2ClI in acetonitrile solution. A coparision was made between density-functional theroy computations for portable photoproduct species and the results from a femtosecond transient absorption study to Raman spectra. This comparision indicated that the iso-CH2ClI was aminly produced and associated with the 460 nm transient absorption band.",

author = "Kwok, \{Wai Ming\} and Chensheng Ma and Parker, \{Anthony W.\} and David Phillips and Michael Towrie and Pavel Matousek and Xuming Zheng and Phillips, \{David Lee\}",

year = "2001",

month = may,

day = "1",

doi = "10.1063/1.1362178",

language = "English",

volume = "114",

pages = "7536--7543",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "17",

}

Picosecond time-resolved resonance Raman observation of the iso-CH₂Cl-I and iso-CH₂I-Cl photoproducts from the "photoisomerization" reactions of CH₂ICl in the solution phase. / Kwok, Wai Ming; Ma, Chensheng; Parker, Anthony W. et al.
In: Journal of Chemical Physics, Vol. 114, No. 17, 01.05.2001, p. 7536-7543.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Picosecond time-resolved resonance Raman observation of the iso-CH2Cl-I and iso-CH2I-Cl photoproducts from the "photoisomerization" reactions of CH2ICl in the solution phase

AU - Kwok, Wai Ming

AU - Ma, Chensheng

AU - Parker, Anthony W.

AU - Phillips, David

AU - Towrie, Michael

AU - Matousek, Pavel

AU - Zheng, Xuming

AU - Phillips, David Lee

PY - 2001/5/1

Y1 - 2001/5/1

N2 - A preliminary pecosecond Stokes time-resolved resonance Raman investigation was made of the initial formation and subsequent decay of the photoproduct produced following 267 nm excitaiton of CH2ClI in acetonitrile solution. A coparision was made between density-functional theroy computations for portable photoproduct species and the results from a femtosecond transient absorption study to Raman spectra. This comparision indicated that the iso-CH2ClI was aminly produced and associated with the 460 nm transient absorption band.

AB - A preliminary pecosecond Stokes time-resolved resonance Raman investigation was made of the initial formation and subsequent decay of the photoproduct produced following 267 nm excitaiton of CH2ClI in acetonitrile solution. A coparision was made between density-functional theroy computations for portable photoproduct species and the results from a femtosecond transient absorption study to Raman spectra. This comparision indicated that the iso-CH2ClI was aminly produced and associated with the 460 nm transient absorption band.

UR - https://www.scopus.com/pages/publications/0035335285

U2 - 10.1063/1.1362178

DO - 10.1063/1.1362178

M3 - Journal article

SN - 0021-9606

VL - 114

SP - 7536

EP - 7543

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 17

ER -

Picosecond time-resolved resonance Raman observation of the iso-CH₂Cl-I and iso-CH₂I-Cl photoproducts from the "photoisomerization" reactions of CH₂ICl in the solution phase

Abstract

ASJC Scopus subject areas

More information

Other files and links

Fingerprint

Cite this