Abstract
A preliminary pecosecond Stokes time-resolved resonance Raman investigation was made of the initial formation and subsequent decay of the photoproduct produced following 267 nm excitaiton of CH2ClI in acetonitrile solution. A coparision was made between density-functional theroy computations for portable photoproduct species and the results from a femtosecond transient absorption study to Raman spectra. This comparision indicated that the iso-CH2ClI was aminly produced and associated with the 460 nm transient absorption band.
Original language | English |
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Pages (from-to) | 7536-7543 |
Number of pages | 8 |
Journal | Journal of Chemical Physics |
Volume | 114 |
Issue number | 17 |
DOIs | |
Publication status | Published - 1 May 2001 |
Externally published | Yes |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry