Picosecond time-resolved resonance Raman observation of Iso- CH2Br-I following A-band photodissociation of CH2BrI in the solution phase

Wai Ming Kwok, Chensheng Ma, David Phillips, Anthony W. Parker, Michael Towrie, Pavel Matousek, David Lee Phillips

Research output: Journal article publicationJournal articleAcademic researchpeer-review

36 Citations (Scopus)

Abstract

We present picosecond time-resolved resonance Raman spectra that demonstrate formation of the iso-CH2Br-I species following A-band excitation of bromoiodomethane in cyclohexane solvent at room temperature. The iso-CH2Br-I species is produced within several ps and appears to decay with a half-life on the 2-3 ns time scale. We compare these results to previous studies on solution phase photodissociation of dihalomethanes.
Original languageEnglish
Pages (from-to)292-298
Number of pages7
JournalChemical Physics Letters
Volume341
Issue number3-4
DOIs
Publication statusPublished - 22 Jun 2001
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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