Phosphorus recovered from digestate by hydrothermal processes with struvite crystallization and its potential as a fertilizer

Phosphorus (P) recovery from digestate has attracted considerable interest. In this study, hydrothermal processes in combination with struvite crystallization were performed to promote P solubilization and capture from digestate; its potential as a phosphate-based fertilizer was also investigated. Hydrothermal treatment with HCl and H₂O₂ showed good results for the solubilization of organic and slightly soluble P, and achieved the lowest input energy need (768 kWhkg⁻¹ _P). Struvite crystallization reached 99.3% (Mg²⁺:PO₄ ³⁻1.84:1, pH 9.98). X-ray diffractometry and energy dispersive X-ray spectrometer mapping demonstrated the main precipitate component was struvite. For the fertilization of maize, P utilization from struvite was 19.0%. Light microscope analysis revealed that appropriate amounts of struvite may have an influence on the growth of the primary root. Overall, 16.6% of total P was recovered after P was solubilized, captured and made available.