TY - JOUR
T1 - Phosphorescent Manganese(II) Complexes and Their Emerging Applications
AU - Tao, Peng
AU - Liu, Shu Juan
AU - Wong, Wai Yeung
N1 - Funding Information:
The authors acknowledge the National Natural Science Foundation of China (Nos. 61905120, 51873176, and 61775101), the Hong Kong Research Grants Council (No. PolyU 153058/19P), the Hong Kong Polytechnic University (No. 1-ZE1C), Clarea Au for the Endowed Professorship in Energy (No. 847S), and Natural Science Foundation of Jiangsu Province of China (No. BK20190740) for financial support.
Publisher Copyright:
© 2020 Wiley-VCH GmbH
Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/10/1
Y1 - 2020/10/1
N2 - Phosphorescent manganese(II) complexes are emerging as a new generation of phosphorescent materials showing great potentials in many applications, owing to their unique features including highly efficient phosphorescence, diverse structural/molecular design, and ease of synthesis, structural diversity, rich physical properties (e.g., triboluminescence, stimuli-responsivity, etc.), high abundance, and low cost. The research on phosphorescent manganese(II) complexes is just in its infancy but rapidly flourishing indeed, and their potential applications are also emerging in many aspects. Herein, the recent progress on the molecular design of new manganese(II) complex-based materials, mechanism of phosphorescence, photophysical properties, and their representative applications is highlighted, which covers topics such as: i) structural features and photophysics of phosphorescent manganese(II) complexes; ii) molecular design strategies of phosphorescent manganese(II) complexes (e.g., neutral complexes, ionic complexes, coordination polymers, and other types of complexes); and iii) their emerging applications in the fields of organic electroluminescence, information recording and security protection, temperature sensors. Finally, some perspectives together with future research focus of the field are described.
AB - Phosphorescent manganese(II) complexes are emerging as a new generation of phosphorescent materials showing great potentials in many applications, owing to their unique features including highly efficient phosphorescence, diverse structural/molecular design, and ease of synthesis, structural diversity, rich physical properties (e.g., triboluminescence, stimuli-responsivity, etc.), high abundance, and low cost. The research on phosphorescent manganese(II) complexes is just in its infancy but rapidly flourishing indeed, and their potential applications are also emerging in many aspects. Herein, the recent progress on the molecular design of new manganese(II) complex-based materials, mechanism of phosphorescence, photophysical properties, and their representative applications is highlighted, which covers topics such as: i) structural features and photophysics of phosphorescent manganese(II) complexes; ii) molecular design strategies of phosphorescent manganese(II) complexes (e.g., neutral complexes, ionic complexes, coordination polymers, and other types of complexes); and iii) their emerging applications in the fields of organic electroluminescence, information recording and security protection, temperature sensors. Finally, some perspectives together with future research focus of the field are described.
KW - energy transfer
KW - manganese(II) complexes
KW - phosphorescence
KW - structure-property relationships
KW - triboluminescence
UR - http://www.scopus.com/inward/record.url?scp=85089462475&partnerID=8YFLogxK
U2 - 10.1002/adom.202000985
DO - 10.1002/adom.202000985
M3 - Review article
AN - SCOPUS:85089462475
SN - 2195-1071
VL - 8
JO - Advanced Optical Materials
JF - Advanced Optical Materials
IS - 20
M1 - 2000985
ER -