Phase transition, piezoelectric, and multiferroic properties of La(Co0.5Mn0.5)O3-modified BiFeO3-BaTiO3 lead-free ceramics

Lingling Luo; Na Jiang; Xiao Zou; Dongliang Shi; Ting Sun; Qiaoji Zheng; Chenggang Xu; Kwok Ho Lam; Dunmin Lin

doi:10.1002/pssa.201532127

Phase transition, piezoelectric, and multiferroic properties of La(Co_0.5Mn_0.5)O₃-modified BiFeO₃-BaTiO₃ lead-free ceramics

Lingling Luo, Na Jiang, Xiao Zou, Dongliang Shi, Ting Sun, Qiaoji Zheng, Chenggang Xu, Kwok Ho Lam, Dunmin Lin

The Hong Kong Polytechnic University

Research output: Journal article publication › Journal article › Academic research › peer-review

16 Citations (Scopus)

Abstract

KGaA, Weinheim. (0.75-x)BiFeO₃-0.25BaTiO₃-xLa(Co_0.5Mn_0.5)O₃ + 1 mol% MnO₂ lead-free ceramics (x = 0-0.10) were synthesized by a conventional solid-state reaction route and the effects of La(Co_0.5Mn_0.5)O₃ on phase transition, piezoelectric, ferroelectric, and multiferroic properties of the ceramics were investigated. The ceramics can be well sintered at 960°C for 2 h. After the addition of La(Co_0.5Mn_0.5)O₃, the crystal structure of the ceramics is transformed from rhombohedral (space group R3c) to orthorhombic symmetry (space group Amm2), and the morphotropic phase boundary (MPB) of rhombohedral and orthorhombic phases is formed at x = 0.01-0.03. The dielectric peak of the ceramics was found to become diffusive with increasing x. The ceramics with x = 0-0.03 possess strong piezoelectricity with d₃₃ of 95-108 pC N^-1, strong ferroelectricity with P_r of 2.2-18.1 μC cm^-2, considerable magnetoelectric coefficient of 372-672 mV/cmOe, and high Curie temperature of 523-659°C, showing potential applications in multiferroic devices.

Original language	English
Pages (from-to)	2012-2022
Number of pages	11
Journal	Physica Status Solidi (A) Applications and Materials Science
Volume	212
Issue number	9
DOIs	https://doi.org/10.1002/pssa.201532127
Publication status	Published - 1 Sept 2015

Keywords

ferroelectric properties
lead-free ceramics
magnetic properties
multiferroics
phase transitions
piezoelectric properties

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Surfaces and Interfaces
Surfaces, Coatings and Films
Electrical and Electronic Engineering
Materials Chemistry

More information

10.1002/pssa.201532127

Cite this

@article{82de0355e9894c2f8c42de4404e86da4,

title = "Phase transition, piezoelectric, and multiferroic properties of La(Co0.5Mn0.5)O3-modified BiFeO3-BaTiO3 lead-free ceramics",

abstract = "KGaA, Weinheim. (0.75-x)BiFeO3-0.25BaTiO3-xLa(Co0.5Mn0.5)O3 + 1 mol% MnO2 lead-free ceramics (x = 0-0.10) were synthesized by a conventional solid-state reaction route and the effects of La(Co0.5Mn0.5)O3 on phase transition, piezoelectric, ferroelectric, and multiferroic properties of the ceramics were investigated. The ceramics can be well sintered at 960°C for 2 h. After the addition of La(Co0.5Mn0.5)O3, the crystal structure of the ceramics is transformed from rhombohedral (space group R3c) to orthorhombic symmetry (space group Amm2), and the morphotropic phase boundary (MPB) of rhombohedral and orthorhombic phases is formed at x = 0.01-0.03. The dielectric peak of the ceramics was found to become diffusive with increasing x. The ceramics with x = 0-0.03 possess strong piezoelectricity with d33 of 95-108 pC N-1, strong ferroelectricity with Pr of 2.2-18.1 μC cm-2, considerable magnetoelectric coefficient of 372-672 mV/cmOe, and high Curie temperature of 523-659°C, showing potential applications in multiferroic devices.",

keywords = "ferroelectric properties, lead-free ceramics, magnetic properties, multiferroics, phase transitions, piezoelectric properties",

author = "Lingling Luo and Na Jiang and Xiao Zou and Dongliang Shi and Ting Sun and Qiaoji Zheng and Chenggang Xu and Lam, {Kwok Ho} and Dunmin Lin",

year = "2015",

month = sep,

day = "1",

doi = "10.1002/pssa.201532127",

language = "English",

volume = "212",

pages = "2012--2022",

journal = "Physica Status Solidi (A) Applications and Materials Science",

issn = "1862-6300",

publisher = "Wiley-VCH Verlag",

number = "9",

}

Phase transition, piezoelectric, and multiferroic properties of La(Co_0.5Mn_0.5)O₃-modified BiFeO₃-BaTiO₃ lead-free ceramics. / Luo, Lingling; Jiang, Na; Zou, Xiao et al.
In: Physica Status Solidi (A) Applications and Materials Science, Vol. 212, No. 9, 01.09.2015, p. 2012-2022.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Phase transition, piezoelectric, and multiferroic properties of La(Co0.5Mn0.5)O3-modified BiFeO3-BaTiO3 lead-free ceramics

AU - Luo, Lingling

AU - Jiang, Na

AU - Zou, Xiao

AU - Shi, Dongliang

AU - Sun, Ting

AU - Zheng, Qiaoji

AU - Xu, Chenggang

AU - Lam, Kwok Ho

AU - Lin, Dunmin

PY - 2015/9/1

Y1 - 2015/9/1

N2 - KGaA, Weinheim. (0.75-x)BiFeO3-0.25BaTiO3-xLa(Co0.5Mn0.5)O3 + 1 mol% MnO2 lead-free ceramics (x = 0-0.10) were synthesized by a conventional solid-state reaction route and the effects of La(Co0.5Mn0.5)O3 on phase transition, piezoelectric, ferroelectric, and multiferroic properties of the ceramics were investigated. The ceramics can be well sintered at 960°C for 2 h. After the addition of La(Co0.5Mn0.5)O3, the crystal structure of the ceramics is transformed from rhombohedral (space group R3c) to orthorhombic symmetry (space group Amm2), and the morphotropic phase boundary (MPB) of rhombohedral and orthorhombic phases is formed at x = 0.01-0.03. The dielectric peak of the ceramics was found to become diffusive with increasing x. The ceramics with x = 0-0.03 possess strong piezoelectricity with d33 of 95-108 pC N-1, strong ferroelectricity with Pr of 2.2-18.1 μC cm-2, considerable magnetoelectric coefficient of 372-672 mV/cmOe, and high Curie temperature of 523-659°C, showing potential applications in multiferroic devices.

AB - KGaA, Weinheim. (0.75-x)BiFeO3-0.25BaTiO3-xLa(Co0.5Mn0.5)O3 + 1 mol% MnO2 lead-free ceramics (x = 0-0.10) were synthesized by a conventional solid-state reaction route and the effects of La(Co0.5Mn0.5)O3 on phase transition, piezoelectric, ferroelectric, and multiferroic properties of the ceramics were investigated. The ceramics can be well sintered at 960°C for 2 h. After the addition of La(Co0.5Mn0.5)O3, the crystal structure of the ceramics is transformed from rhombohedral (space group R3c) to orthorhombic symmetry (space group Amm2), and the morphotropic phase boundary (MPB) of rhombohedral and orthorhombic phases is formed at x = 0.01-0.03. The dielectric peak of the ceramics was found to become diffusive with increasing x. The ceramics with x = 0-0.03 possess strong piezoelectricity with d33 of 95-108 pC N-1, strong ferroelectricity with Pr of 2.2-18.1 μC cm-2, considerable magnetoelectric coefficient of 372-672 mV/cmOe, and high Curie temperature of 523-659°C, showing potential applications in multiferroic devices.

KW - ferroelectric properties

KW - lead-free ceramics

KW - magnetic properties

KW - multiferroics

KW - phase transitions

KW - piezoelectric properties

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U2 - 10.1002/pssa.201532127

DO - 10.1002/pssa.201532127

M3 - Journal article

SN - 1862-6300

VL - 212

SP - 2012

EP - 2022

JO - Physica Status Solidi (A) Applications and Materials Science

JF - Physica Status Solidi (A) Applications and Materials Science

IS - 9

ER -