Abstract
Aluminium was laser clad on a pure zirconium substrate using the blown powder method. The microstructure across the laser-clad coating was studied. Starting from the bottom to the top surface of the coating, a series of phase evolutions had occurred: (Zr) → (Zr) + AlZr2+ AlZr3→ Al4Zr5+ Al3Zr2→ Al3Zr2+ AlZr2→ Al2Zr → Al2Zr + Al3Zr. This resulted in an epitaxial columnar crystal growth at the re-melt substrate boundary, a band of backward growth Al3Zr2dendrites towards the lower half of the coating, and a two-phase eutectic dendritic growth of Al2Zr + Al3Zr towards the top of the coating. The evolution of the various phases and microstructures is discussed in conjunction with the Al-Zr phase diagram, the criteria for planar interface instability, and the theory of eutectic growth under rapid solidification conditions (the TMK model).
Original language | English |
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Pages (from-to) | 3705-3710 |
Number of pages | 6 |
Journal | Journal of Alloys and Compounds |
Volume | 509 |
Issue number | 8 |
DOIs | |
Publication status | Published - 24 Feb 2011 |
Keywords
- Aluminium
- Dendrite growth
- Intermetallics
- Laser cladding
- Phase evolution
- Zirconium
ASJC Scopus subject areas
- Mechanics of Materials
- Mechanical Engineering
- Metals and Alloys
- Materials Chemistry