Perovskite Photovoltachromic Supercapacitor with All-Transparent Electrodes

Feichi Zhou, Zhiwei Ren, Yuda Zhao, Xinpeng Shen, Aiwu Wang, Yang Yang Li, Charles Surya, Yang Chai

Research output: Journal article publicationJournal articleAcademic researchpeer-review

106 Citations (Scopus)

Abstract

Photovoltachromic cells (PVCCs) are of great interest for the self-powered smart windows of architectures and vehicles, which require widely tunable transmittance and automatic color change under photostimuli. Organolead halide perovskite possesses high light absorption coefficient and enables thin and semitransparent photovoltaic device. In this work, we demonstrate co-anode and co-cathode photovoltachromic supercapacitors (PVCSs) by vertically integrating a perovskite solar cell (PSC) with MoO3/Au/MoO3transparent electrode and electrochromic supercapacitor. The PVCSs provide a seamless integration of energy harvesting/storage device, automatic and wide color tunability, and enhanced photostability of PSCs. Compared with conventional PVCC, the counter electrodes of our PVCSs provide sufficient balancing charge, eliminate the necessity of reverse bias voltage for bleaching the device, and realize reasonable in situ energy storage. The color states of PVCSs not only indicate the amount of energy stored and energy consumed in real time, but also enhance the photostability of photovoltaic component by preventing its long-time photoexposure under fully charged state of PVCSs. This work designs PVCS devices for multifunctional smart window applications commonly made of glass.
Original languageEnglish
Pages (from-to)5900-5908
Number of pages9
JournalACS Nano
Volume10
Issue number6
DOIs
Publication statusPublished - 28 Jun 2016

Keywords

  • electrochromic
  • energy storage
  • perovskite solar cell
  • photostability
  • photovoltachromic supercapacitor (PVCS)

ASJC Scopus subject areas

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

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