Pentamethylcyclopentadienyl ruthenium complexes with sulfur- and selenium-donor ligands

Qian Feng Zhang; Florence K.M. Cheung; Wai Yeung Wong; Ian D. Williams; Wa Hung Leung

doi:10.1021/om010054x

Pentamethylcyclopentadienyl ruthenium complexes with sulfur- and selenium-donor ligands

Qian Feng Zhang, Florence K.M. Cheung, Wai Yeung Wong, Ian D. Williams, Wa Hung Leung

Research output: Journal article publication › Journal article › Academic research › peer-review

38 Citations (Scopus)

Abstract

Treatment of [Cp*Ru(NO)Cl2] (Cp* = η5-C5Me5) with NaQAr or LiQAr (Q = S, Se, Te; Ar = C6F4H or Ph) affords [Cp*Ru(NO)(QAr)2]. Interactions of [Cp*Ru(NO)(SC6F4H)2] with PR3 (R = Ph or Me) give [Cp*Ru(PR3)2(SC6 F4H)] via phosphoraminate intermediates. The crystal structures of [Cp*Ru(NO)(SC6F4H)2] and [Cp*Ru(PMe3)2(SC6F4H)] have been determined. Treatment of [Cp*Ru(MeCN)3][PF6] with HN[SeP(i-Pr)2]2 affords a novel Cp*Ru(IV) complex, [Cp*Ru{η2-Se2P(i-Pr)2} {η2-SeP(i-Pr)2}][PF6], which has been characterized by X-ray crystallography.

Original language	English
Pages (from-to)	3777-3781
Number of pages	5
Journal	Organometallics
Volume	20
Issue number	17
DOIs	https://doi.org/10.1021/om010054x
Publication status	Published - 20 Aug 2001
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om010054x

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@article{92c95b64ea0544fc83f623f4d08e328d,

title = "Pentamethylcyclopentadienyl ruthenium complexes with sulfur- and selenium-donor ligands",

abstract = "Treatment of [Cp*Ru(NO)Cl2] (Cp* = η5-C5Me5) with NaQAr or LiQAr (Q = S, Se, Te; Ar = C6F4H or Ph) affords [Cp*Ru(NO)(QAr)2]. Interactions of [Cp*Ru(NO)(SC6F4H)2] with PR3 (R = Ph or Me) give [Cp*Ru(PR3)2(SC6 F4H)] via phosphoraminate intermediates. The crystal structures of [Cp*Ru(NO)(SC6F4H)2] and [Cp*Ru(PMe3)2(SC6F4H)] have been determined. Treatment of [Cp*Ru(MeCN)3][PF6] with HN[SeP(i-Pr)2]2 affords a novel Cp*Ru(IV) complex, [Cp*Ru{η2-Se2P(i-Pr)2} {η2-SeP(i-Pr)2}][PF6], which has been characterized by X-ray crystallography.",

author = "Zhang, {Qian Feng} and Cheung, {Florence K.M.} and Wong, {Wai Yeung} and Williams, {Ian D.} and Leung, {Wa Hung}",

year = "2001",

month = aug,

day = "20",

doi = "10.1021/om010054x",

language = "English",

volume = "20",

pages = "3777--3781",

journal = "Organometallics",

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publisher = "American Chemical Society",

number = "17",

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TY - JOUR

T1 - Pentamethylcyclopentadienyl ruthenium complexes with sulfur- and selenium-donor ligands

AU - Zhang, Qian Feng

AU - Cheung, Florence K.M.

AU - Wong, Wai Yeung

AU - Williams, Ian D.

AU - Leung, Wa Hung

PY - 2001/8/20

Y1 - 2001/8/20

N2 - Treatment of [Cp*Ru(NO)Cl2] (Cp* = η5-C5Me5) with NaQAr or LiQAr (Q = S, Se, Te; Ar = C6F4H or Ph) affords [Cp*Ru(NO)(QAr)2]. Interactions of [Cp*Ru(NO)(SC6F4H)2] with PR3 (R = Ph or Me) give [Cp*Ru(PR3)2(SC6 F4H)] via phosphoraminate intermediates. The crystal structures of [Cp*Ru(NO)(SC6F4H)2] and [Cp*Ru(PMe3)2(SC6F4H)] have been determined. Treatment of [Cp*Ru(MeCN)3][PF6] with HN[SeP(i-Pr)2]2 affords a novel Cp*Ru(IV) complex, [Cp*Ru{η2-Se2P(i-Pr)2} {η2-SeP(i-Pr)2}][PF6], which has been characterized by X-ray crystallography.

AB - Treatment of [Cp*Ru(NO)Cl2] (Cp* = η5-C5Me5) with NaQAr or LiQAr (Q = S, Se, Te; Ar = C6F4H or Ph) affords [Cp*Ru(NO)(QAr)2]. Interactions of [Cp*Ru(NO)(SC6F4H)2] with PR3 (R = Ph or Me) give [Cp*Ru(PR3)2(SC6 F4H)] via phosphoraminate intermediates. The crystal structures of [Cp*Ru(NO)(SC6F4H)2] and [Cp*Ru(PMe3)2(SC6F4H)] have been determined. Treatment of [Cp*Ru(MeCN)3][PF6] with HN[SeP(i-Pr)2]2 affords a novel Cp*Ru(IV) complex, [Cp*Ru{η2-Se2P(i-Pr)2} {η2-SeP(i-Pr)2}][PF6], which has been characterized by X-ray crystallography.

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U2 - 10.1021/om010054x

DO - 10.1021/om010054x

M3 - Journal article

SN - 0276-7333

VL - 20

SP - 3777

EP - 3781

JO - Organometallics

JF - Organometallics

IS - 17

ER -

Pentamethylcyclopentadienyl ruthenium complexes with sulfur- and selenium-donor ligands

Abstract

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