Abstract
A free surface induces enhanced dynamics in glass formers. We study the dynamical enhancement of glassy films with a distinguishable-particle lattice model of glass free of elastic effects. We demonstrate that the thickness of the surface mobile layer depends on temperature differently under different definitions, although all are based on local structure relaxation rate. The rate can be fitted to a double exponential form with an exponential-of-power-law tail. Our approach and results exclude elasticity as the unique mechanism for the tail. Layer-resolved particle hopping rate, potentially a key measure for activated hopping, is also studied but it exhibits much shallower surface effects.
| Original language | English |
|---|---|
| Article number | 234502 |
| Journal | Journal of Chemical Physics |
| Volume | 162 |
| Issue number | 23 |
| DOIs | |
| Publication status | Published - 21 Jun 2025 |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry
Fingerprint
Dive into the research topics of 'Penetration of surface effects on structural relaxation and particle hops in glassy films'. Together they form a unique fingerprint.Cite this
- APA
- Author
- BIBTEX
- Harvard
- Standard
- RIS
- Vancouver