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Penetration of surface effects on structural relaxation and particle hops in glassy films

  • Qiang Zhai
  • , Hai Yao Deng
  • , Xin Yuan Gao
  • , Leo S.I. Lam
  • , Sen Yang
  • , Ke Yan
  • , Chi Hang Lam

Research output: Journal article publicationJournal articleAcademic researchpeer-review

Abstract

A free surface induces enhanced dynamics in glass formers. We study the dynamical enhancement of glassy films with a distinguishable-particle lattice model of glass free of elastic effects. We demonstrate that the thickness of the surface mobile layer depends on temperature differently under different definitions, although all are based on local structure relaxation rate. The rate can be fitted to a double exponential form with an exponential-of-power-law tail. Our approach and results exclude elasticity as the unique mechanism for the tail. Layer-resolved particle hopping rate, potentially a key measure for activated hopping, is also studied but it exhibits much shallower surface effects.

Original languageEnglish
Article number234502
JournalJournal of Chemical Physics
Volume162
Issue number23
DOIs
Publication statusPublished - 21 Jun 2025

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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