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Palladium(II)-catalyzed switchable mono-/diselenylation of arenes controlled by solvent effects This paper is dedicated to the memory of Prof. the Lord Lewis of Newnham, FRS.

Research output: Journal article publicationJournal articleAcademic researchpeer-review

Abstract

Organic selenides were efficient regioselective synthesized by palladium-catalyzed switchable mono- and diselenylation of arenes sp2C-H bonds through simply tuning the DMSO to water ratio. The present protocol was also successfully extended to the monoselenylation of 2-phenoxypyridines, which bore a removable directing group, in modest yields.
Original languageEnglish
Pages (from-to)66-73
Number of pages8
JournalJournal of Organometallic Chemistry
Volume812
DOIs
Publication statusPublished - 15 Jun 2016

Keywords

  • Organic selenides
  • Palladium
  • Selenylation
  • Solvent effects

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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