Palladium(II)-catalyzed switchable mono-/diselenylation of arenes controlled by solvent effects This paper is dedicated to the memory of Prof. the Lord Lewis of Newnham, FRS.

Weiwei Jin; Poonnapa Zheng; Ga Lai Law; Wing Tak Wong

doi:10.1016/j.jorganchem.2015.09.040

Palladium(II)-catalyzed switchable mono-/diselenylation of arenes controlled by solvent effects This paper is dedicated to the memory of Prof. the Lord Lewis of Newnham, FRS.

Weiwei Jin, Poonnapa Zheng, Ga Lai Law, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

20 Citations (Scopus)

Abstract

Organic selenides were efficient regioselective synthesized by palladium-catalyzed switchable mono- and diselenylation of arenes sp2C-H bonds through simply tuning the DMSO to water ratio. The present protocol was also successfully extended to the monoselenylation of 2-phenoxypyridines, which bore a removable directing group, in modest yields.

Original language	English
Pages (from-to)	66-73
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	812
DOIs	https://doi.org/10.1016/j.jorganchem.2015.09.040
Publication status	Published - 15 Jun 2016

Keywords

Organic selenides
Palladium
Selenylation
Solvent effects

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2015.09.040

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title = "Palladium(II)-catalyzed switchable mono-/diselenylation of arenes controlled by solvent effects This paper is dedicated to the memory of Prof. the Lord Lewis of Newnham, FRS.",

abstract = "Organic selenides were efficient regioselective synthesized by palladium-catalyzed switchable mono- and diselenylation of arenes sp2C-H bonds through simply tuning the DMSO to water ratio. The present protocol was also successfully extended to the monoselenylation of 2-phenoxypyridines, which bore a removable directing group, in modest yields.",

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Palladium(II)-catalyzed switchable mono-/diselenylation of arenes controlled by solvent effects This paper is dedicated to the memory of Prof. the Lord Lewis of Newnham, FRS. / Jin, Weiwei; Zheng, Poonnapa; Law, Ga Lai et al.
In: Journal of Organometallic Chemistry, Vol. 812, 15.06.2016, p. 66-73.

Research output: Journal article publication › Journal article › Academic research › peer-review

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AU - Zheng, Poonnapa

AU - Law, Ga Lai

AU - Wong, Wing Tak

PY - 2016/6/15

Y1 - 2016/6/15

N2 - Organic selenides were efficient regioselective synthesized by palladium-catalyzed switchable mono- and diselenylation of arenes sp2C-H bonds through simply tuning the DMSO to water ratio. The present protocol was also successfully extended to the monoselenylation of 2-phenoxypyridines, which bore a removable directing group, in modest yields.

AB - Organic selenides were efficient regioselective synthesized by palladium-catalyzed switchable mono- and diselenylation of arenes sp2C-H bonds through simply tuning the DMSO to water ratio. The present protocol was also successfully extended to the monoselenylation of 2-phenoxypyridines, which bore a removable directing group, in modest yields.

KW - Organic selenides

KW - Palladium

KW - Selenylation

KW - Solvent effects

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DO - 10.1016/j.jorganchem.2015.09.040

M3 - Journal article

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EP - 73

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ER -

Palladium(II)-catalyzed switchable mono-/diselenylation of arenes controlled by solvent effects This paper is dedicated to the memory of Prof. the Lord Lewis of Newnham, FRS.

Abstract

Keywords

ASJC Scopus subject areas

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