Abstract
Organic selenides were efficient regioselective synthesized by palladium-catalyzed switchable mono- and diselenylation of arenes sp2C-H bonds through simply tuning the DMSO to water ratio. The present protocol was also successfully extended to the monoselenylation of 2-phenoxypyridines, which bore a removable directing group, in modest yields.
Original language | English |
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Pages (from-to) | 66-73 |
Number of pages | 8 |
Journal | Journal of Organometallic Chemistry |
Volume | 812 |
DOIs | |
Publication status | Published - 15 Jun 2016 |
Keywords
- Organic selenides
- Palladium
- Selenylation
- Solvent effects
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry