Palladium-catalyzed reductive cleavage of tosylated arenes using isopropanol as the mild reducing agent

Wing Kin Chow; Chau Ming So; Chak Po Lau; Fuk Yee Kwong

doi:10.1039/c4qo00103f

Palladium-catalyzed reductive cleavage of tosylated arenes using isopropanol as the mild reducing agent

Wing Kin Chow, Chau Ming So, Chak Po Lau, Fuk Yee Kwong

Research output: Journal article publication › Journal article › Academic research › peer-review

20 Citations (Scopus)

Abstract

This journal is The deoxygenation of tosylated arenes catalyzed by a palladium complex is described. This method represents one of the first general examples of reductive C-O bond cleavage of aryl tosylates via palladium catalysis. By simply employing isopropanol as a mild reducing agent, a variety of tosylated arenes can be smoothly reduced. Labelling experiments revealed that the H source is isopropanol.

Original language	English
Pages (from-to)	464-467
Number of pages	4
Journal	Organic Chemistry Frontiers
Volume	1
Issue number	5
DOIs	https://doi.org/10.1039/c4qo00103f
Publication status	Published - 1 Jan 2014

ASJC Scopus subject areas

Organic Chemistry

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10.1039/c4qo00103f

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abstract = "This journal is The deoxygenation of tosylated arenes catalyzed by a palladium complex is described. This method represents one of the first general examples of reductive C-O bond cleavage of aryl tosylates via palladium catalysis. By simply employing isopropanol as a mild reducing agent, a variety of tosylated arenes can be smoothly reduced. Labelling experiments revealed that the H source is isopropanol.",

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AU - So, Chau Ming

AU - Lau, Chak Po

AU - Kwong, Fuk Yee

PY - 2014/1/1

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N2 - This journal is The deoxygenation of tosylated arenes catalyzed by a palladium complex is described. This method represents one of the first general examples of reductive C-O bond cleavage of aryl tosylates via palladium catalysis. By simply employing isopropanol as a mild reducing agent, a variety of tosylated arenes can be smoothly reduced. Labelling experiments revealed that the H source is isopropanol.

AB - This journal is The deoxygenation of tosylated arenes catalyzed by a palladium complex is described. This method represents one of the first general examples of reductive C-O bond cleavage of aryl tosylates via palladium catalysis. By simply employing isopropanol as a mild reducing agent, a variety of tosylated arenes can be smoothly reduced. Labelling experiments revealed that the H source is isopropanol.

UR - https://www.scopus.com/pages/publications/84921418084

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DO - 10.1039/c4qo00103f

M3 - Journal article

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VL - 1

SP - 464

EP - 467

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 5

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Palladium-catalyzed reductive cleavage of tosylated arenes using isopropanol as the mild reducing agent

Abstract

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